Photo-thermal haptotropism in cyclopentadienylcobalt complexes of linear phenylenes: Intercyelobutadiene metal migration

Thomas A. Albright; Peter I. Dosa; Tom N. Grossmann; Victor N. Khrustalev; Oluwakemi A. Oloba; Robin Padilla; Renaud Paubelle; Amnon Stanger; Tatiana V. Timofeeva; K. Peter C. Vollhardt

doi:10.1002/anie.200905088

Photo-thermal haptotropism in cyclopentadienylcobalt complexes of linear phenylenes: Intercyelobutadiene metal migration

Thomas A. Albright, Peter I. Dosa, Tom N. Grossmann, Victor N. Khrustalev, Oluwakemi A. Oloba, Robin Padilla, Renaud Paubelle, Amnon Stanger, Tatiana V. Timofeeva, K. Peter C. Vollhardt

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Abstract

(figure represented) The CpCo-shuffle: {CpCo} complexes of linear [3]- and [5]phenylene undergo a light-induced haptotropic migration from a more strongly bound cyclobutadiene moiety to a less strongly bound (see scheme). The shift is thermally reversible and proceeds along the periphery of the intervening arene rings. As such, the systems constitute photo-thermal storage systems, as well the first examples of cyclobutadiene-to-cyclobutadiene haptotropism.

Original language	English (US)
Pages (from-to)	9853-9857+9765
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	52
DOIs	https://doi.org/10.1002/anie.200905088
State	Published - Dec 21 2009
Externally published	Yes

Keywords

Ab initio calculations
Arene ligands
Haptotropism
Isomerization
Photochemistry

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10.1002/anie.200905088

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Albright, T. A., Dosa, P. I., Grossmann, T. N., Khrustalev, V. N., Oloba, O. A., Padilla, R., Paubelle, R., Stanger, A., Timofeeva, T. V., & Vollhardt, K. P. C. (2009). Photo-thermal haptotropism in cyclopentadienylcobalt complexes of linear phenylenes: Intercyelobutadiene metal migration. Angewandte Chemie - International Edition, 48(52), 9853-9857+9765. https://doi.org/10.1002/anie.200905088

Albright, TA, Dosa, PI, Grossmann, TN, Khrustalev, VN, Oloba, OA, Padilla, R, Paubelle, R, Stanger, A, Timofeeva, TV & Vollhardt, KPC 2009, 'Photo-thermal haptotropism in cyclopentadienylcobalt complexes of linear phenylenes: Intercyelobutadiene metal migration', Angewandte Chemie - International Edition, vol. 48, no. 52, pp. 9853-9857+9765. https://doi.org/10.1002/anie.200905088

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abstract = "(figure represented) The CpCo-shuffle: {CpCo} complexes of linear [3]- and [5]phenylene undergo a light-induced haptotropic migration from a more strongly bound cyclobutadiene moiety to a less strongly bound (see scheme). The shift is thermally reversible and proceeds along the periphery of the intervening arene rings. As such, the systems constitute photo-thermal storage systems, as well the first examples of cyclobutadiene-to-cyclobutadiene haptotropism.",

keywords = "Ab initio calculations, Arene ligands, Haptotropism, Isomerization, Photochemistry",

author = "Albright, {Thomas A.} and Dosa, {Peter I.} and Grossmann, {Tom N.} and Khrustalev, {Victor N.} and Oloba, {Oluwakemi A.} and Robin Padilla and Renaud Paubelle and Amnon Stanger and Timofeeva, {Tatiana V.} and Vollhardt, {K. Peter C.}",

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T1 - Photo-thermal haptotropism in cyclopentadienylcobalt complexes of linear phenylenes

T2 - Intercyelobutadiene metal migration

AU - Albright, Thomas A.

AU - Dosa, Peter I.

AU - Grossmann, Tom N.

AU - Khrustalev, Victor N.

AU - Oloba, Oluwakemi A.

AU - Padilla, Robin

AU - Paubelle, Renaud

AU - Stanger, Amnon

AU - Timofeeva, Tatiana V.

AU - Vollhardt, K. Peter C.

PY - 2009/12/21

Y1 - 2009/12/21

N2 - (figure represented) The CpCo-shuffle: {CpCo} complexes of linear [3]- and [5]phenylene undergo a light-induced haptotropic migration from a more strongly bound cyclobutadiene moiety to a less strongly bound (see scheme). The shift is thermally reversible and proceeds along the periphery of the intervening arene rings. As such, the systems constitute photo-thermal storage systems, as well the first examples of cyclobutadiene-to-cyclobutadiene haptotropism.

AB - (figure represented) The CpCo-shuffle: {CpCo} complexes of linear [3]- and [5]phenylene undergo a light-induced haptotropic migration from a more strongly bound cyclobutadiene moiety to a less strongly bound (see scheme). The shift is thermally reversible and proceeds along the periphery of the intervening arene rings. As such, the systems constitute photo-thermal storage systems, as well the first examples of cyclobutadiene-to-cyclobutadiene haptotropism.

KW - Ab initio calculations

KW - Arene ligands

KW - Haptotropism

KW - Isomerization

KW - Photochemistry

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Photo-thermal haptotropism in cyclopentadienylcobalt complexes of linear phenylenes: Intercyelobutadiene metal migration

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