Petrology, isotope characteristics, and K-Ar ages of the Maranhão, northern Brazil, Mesozoic basalt province

Northern Brazil contains remnants of Mesozoic flood basalts and hypabyssal rocks that were apparently emplaced during tectonism related to opening of the Atlantic Ocean. Analyses and new K-Ar ages reveal that this ∼700x250 km Maranhão province (5°-8°S) has low-Ti basalts (∼1.1 wt% TiO₂) in the western part that range about 160 to 190 Ma, and high-Ti basalts (3.4-4.4 wt% TiO₂) in the eastern part about 115-122 Ma. Low-Ti basalt compositions are less evolved and have a smaller range, Mg# 62-56, than the high-Ti basalts, Mg# 44-33. General characteristics of the least evolved members of low- and high-Ti groups include, respectively, Zr 100 and 250 ppm, Sr 225 and 475 ppm, Ba 200 and 500 ppm, Nb 10 and 26 ppm, Y 29 and 36 ppm, La/Yb_(n) 4.2 and 8.8, where La_(n) is 30 and 90. Overall compositions resemble the low- and high-Ti basaltic rocks of the Mesozoic Serra Geral (Paraná) province in southern Brazil. The Maranhão low-Ti basalts have more radiogenic Sr and Pb and higher δ¹⁸O than the high-Ti basalts. Respectively, low- vs high-Ti: e{open}_Sr26-54 vs 15-18; ²⁰⁶Pb/²⁰⁴Pb=18.25-.78 vs 18.22-.24; and δ¹⁸O 8.9-12.6 vs 6.5-8.6. Nd isotopes overlap: e{open}_Nd-1.6 to -3.8 vs -2.1 to -3. Ages, compositions, and isotopes indicate that the low- and high-Ti groups had independent parentages from enriched subcontinental mantle. However, both groups can be modeled from one source composition if low-Ti basalt isotopes reflect crustal contamination, and if the parentages for each group were picritic liquids that represent either higher (for low-Ti) or lower (for high-Ti) percentages of melting of that single source. When comparing Pb isotopes of Maranhão and Serra Geral high-Ti basalts (uncontaminated) to evaluate the DUPAL anomaly, Maranhão has Pb Δ7/4=4.6-11, and Pb Δ8/4=72-87; Serra Geral has Pb Δ7/4=10-13, and Pb Δ8/4=95-125. The small difference is not enough to conform to DUPAL contours, and is inconsistent with large-scale isotopic heterogeneity of mantle beneath Brazil prior to rifting of South America from Africa. Maranhão low-Ti magmas probably relate to the opening of central North Atlantic, and high-Ti magmas to the opening of equatorial Atlantic. The proposed greater percentage of source melting for low-Ti basalts may reflect a Triassic-Jurassic hotspot, while lesser melting for high-Ti magmas may relate to Cretaceous decompressional (rifting) melting.