Peridotites and basalts reveal broad congruence between two independent records of mantle fO2 despite local redox heterogeneity

Suzanne K. Birner, Elizabeth Cottrell, Jessica M. Warren, Katherine A. Kelley, Fred A. Davis

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

The oxygen fugacity (fO2) of the oceanic upper mantle has fundamental implications for the production of magmas and evolution of the Earth's interior and exterior. Mid-ocean ridge basalts and peridotites sample the oceanic upper mantle, and retain a record of oxygen fugacity. While fO2 has been calculated for mid-ocean ridge basalts worldwide (>200 locations), ridge peridotites have been comparatively less well studied (33 samples from 11 locations), and never in the same geographic location as basalts. In order to determine whether peridotites and basalts from mid-ocean ridges record congruent information about the fO2 of the Earth's interior, we analyzed 31 basalts and 41 peridotites from the Oblique Segment of the Southwest Indian Ridge. By measuring basalts and peridotites from the same ridge segment, we can compare samples with maximally similar petrogenetic histories. We project the composition and oxygen fugacity of each lithology back to source conditions, and evaluate the effects of factors such as subsolidus diffusion in peridotites and fractional crystallization in basalts. We find that, on average, basalts and peridotites from the Oblique Segment both reflect a source mantle very near the quartz–fayalite–magnetite (QFM) buffer. However, peridotites record a significantly wider range of values (nearly 3 orders of magnitude in fO2), with a single dredge recording a range in fO2 greater than that previously reported for mid-ocean ridge peridotites worldwide. This suggests that mantle fO2 may be heterogeneous on relatively short length scales, and that this heterogeneity may be obscured within aggregated basalt melts. We further suggest that the global peridotite fO2 dataset may not provide a representative sample of average basalt-source mantle. Our study motivates further investigation of the fO2 recorded by ridge peridotites, as peridotites record information about the fO2 of the Earth's interior that cannot be gleaned from analysis of basalts alone.

Original languageEnglish (US)
Pages (from-to)172-189
Number of pages18
JournalEarth and Planetary Science Letters
Volume494
DOIs
StatePublished - Jul 15 2018

Bibliographical note

Funding Information:
Funding: We gratefully acknowledge National Science Foundation the support through award OCE-1433212 (to E.C. and F.D.), OCE-1434199 and OCE-1620276 (to J.M.W.), and OCE-1433182 (to K.K.). X26A was supported by the U.S. Department of Energy (DOE) – Geosciences (DE-FG02-92ER14244 to The University of Chicago – CARS). Use of the NSLS was supported by The U.S. Department of Energy (DOE) Office of Science under Contract No. DE-AC02-98CH10886. GeoSoilEnviroCARS is supported by the National Science Foundation – Earth Sciences (EAR-1634415) and U.S. Department of Energy – GeoSciences (DE-FG02-94ER14466). Use of the Advanced Photon Source was supported by DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357. We additionally thank Bernard Wood and an anonymous reviewer for their insightful feedback, and we thank Michael Bickle for editorial handing.

Funding Information:
Funding: We gratefully acknowledge National Science Foundation the support through award OCE-1433212 (to E.C. and F.D.), OCE-1434199 and OCE-1620276 (to J.M.W.), and OCE-1433182 (to K.K.). X26A was supported by the U.S. Department of Energy (DOE) – Geosciences ( DE-FG02-92ER14244 to The University of Chicago – CARS). Use of the NSLS was supported by The U.S. Department of Energy ( DOE ) Office of Science under Contract No. DE-AC02-98CH10886 . GeoSoilEnviroCARS is supported by the National Science Foundation – Earth Sciences ( EAR-1634415 ) and U.S. Department of Energy – GeoSciences ( DE-FG02-94ER14466 ). Use of the Advanced Photon Source was supported by DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357 . We additionally thank Bernard Wood and an anonymous reviewer for their insightful feedback, and we thank Michael Bickle for editorial handing.

Publisher Copyright:
© 2018

Keywords

  • basalt
  • mid-ocean ridge
  • oxygen fugacity
  • peridotite
  • upper mantle

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