Perhydroazulenes. 5. Preparation of Perhydroazul-9(10)-en-4-one

Herbert O. House, Joseph H.C. Lee, Don VanDerveer, Jane E. Wissinger

Research output: Contribution to journalArticle

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Abstract

An improved procedure for the preparation of perhydroazul-9(10)-en-4-one is described. Crystal structures were determined for two of the reaction intermediates, 1,6-cyclodecanedione and the cyclic diperoxide derived from 1,6-cyclodecanedione. Measurements of 13C NMR data at various temperatures were used to determine an activation free energy of 14.8 kcal/mol at 298 K for interconversion of the two chair conformers of the cyclic diperoxide.

Original languageEnglish (US)
Pages (from-to)5285-5288
Number of pages4
JournalJournal of Organic Chemistry
Volume48
Issue number26
DOIs
StatePublished - Dec 1983

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