Abstract
It is reported that well-dispersed core-shell Pd@Zn nanoparticles of controllable shell thickness can be synthesized from a Pd/CdSe-ZnO precursor in H2 without using a surfactant: the Pd ensembles on the material surface with electronic modulation by Zn atoms give a methanol turnover frequency (TOF) and selectivity of 3.3 × 10-1 s-1 and 80%, respectively, the yield of which is 2-fold the best reported value over other Pd-based catalysts.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 7698-7702 |
| Number of pages | 5 |
| Journal | Catalysis Science and Technology |
| Volume | 6 |
| Issue number | 21 |
| DOIs | |
| State | Published - Jan 1 2016 |
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Pd@Zn core-shell nanoparticles of controllable shell thickness for catalytic methanol production. / Liao, Fenglin; Wu, Xin Ping; Zheng, Jianwei; Li, Meng Jung; Zeng, Ziyan; Hong, Xinling; Kroner, Anna; Yuan, Youzhu; Gong, Xue Qing; Tsang, Shik Chi Edman.
In: Catalysis Science and Technology, Vol. 6, No. 21, 01.01.2016, p. 7698-7702.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Pd@Zn core-shell nanoparticles of controllable shell thickness for catalytic methanol production
AU - Liao, Fenglin
AU - Wu, Xin Ping
AU - Zheng, Jianwei
AU - Li, Meng Jung
AU - Zeng, Ziyan
AU - Hong, Xinling
AU - Kroner, Anna
AU - Yuan, Youzhu
AU - Gong, Xue Qing
AU - Tsang, Shik Chi Edman
PY - 2016/1/1
Y1 - 2016/1/1
N2 - It is reported that well-dispersed core-shell Pd@Zn nanoparticles of controllable shell thickness can be synthesized from a Pd/CdSe-ZnO precursor in H2 without using a surfactant: the Pd ensembles on the material surface with electronic modulation by Zn atoms give a methanol turnover frequency (TOF) and selectivity of 3.3 × 10-1 s-1 and 80%, respectively, the yield of which is 2-fold the best reported value over other Pd-based catalysts.
AB - It is reported that well-dispersed core-shell Pd@Zn nanoparticles of controllable shell thickness can be synthesized from a Pd/CdSe-ZnO precursor in H2 without using a surfactant: the Pd ensembles on the material surface with electronic modulation by Zn atoms give a methanol turnover frequency (TOF) and selectivity of 3.3 × 10-1 s-1 and 80%, respectively, the yield of which is 2-fold the best reported value over other Pd-based catalysts.
UR - http://www.scopus.com/inward/record.url?scp=84993967040&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84993967040&partnerID=8YFLogxK
U2 - 10.1039/c6cy01832g
DO - 10.1039/c6cy01832g
M3 - Article
AN - SCOPUS:84993967040
VL - 6
SP - 7698
EP - 7702
JO - Catalysis Science and Technology
JF - Catalysis Science and Technology
SN - 2044-4753
IS - 21
ER -