Part I. Chromatography using ultra-stable metal oxide-based stationary phases for HPLC

J. Nawrocki; C. Dunlap; A. McCormick; P. W. Carr

doi:10.1016/j.chroma.2003.11.052

Part I. Chromatography using ultra-stable metal oxide-based stationary phases for HPLC

J. Nawrocki, C. Dunlap, A. McCormick, P. W. Carr

Research output: Contribution to journal › Review article › peer-review

313 Scopus citations

Abstract

The first part of the review contrasts the main drawbacks of silica-based packings such as their relative thermal and chemical instability with excellent stability of metal oxides. The paper concerns mainly ZrO₂, TiO ₂ and Al₂O₃. Methods of preparation of spherical particles for HPLC are described. Surface chemistry of the oxides is, however, very different from that of silica. Ability of the oxides to ion- and ligand exchange is discussed from a chromatographic point of view.

Original language	English (US)
Pages (from-to)	1-30
Number of pages	30
Journal	Journal of Chromatography A
Volume	1028
Issue number	1
DOIs	https://doi.org/10.1016/j.chroma.2003.11.052
State	Published - Feb 27 2004

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Keywords

Alumina
Ion exchange
Ligand exchange
Reviews
Silica
Spherical particles
Stationary phases, LC
Titania
Zirconia

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10.1016/j.chroma.2003.11.052

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abstract = "The first part of the review contrasts the main drawbacks of silica-based packings such as their relative thermal and chemical instability with excellent stability of metal oxides. The paper concerns mainly ZrO2, TiO 2 and Al2O3. Methods of preparation of spherical particles for HPLC are described. Surface chemistry of the oxides is, however, very different from that of silica. Ability of the oxides to ion- and ligand exchange is discussed from a chromatographic point of view.",

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AU - Nawrocki, J.

AU - Dunlap, C.

AU - McCormick, A.

AU - Carr, P. W.

PY - 2004/2/27

Y1 - 2004/2/27

N2 - The first part of the review contrasts the main drawbacks of silica-based packings such as their relative thermal and chemical instability with excellent stability of metal oxides. The paper concerns mainly ZrO2, TiO 2 and Al2O3. Methods of preparation of spherical particles for HPLC are described. Surface chemistry of the oxides is, however, very different from that of silica. Ability of the oxides to ion- and ligand exchange is discussed from a chromatographic point of view.

AB - The first part of the review contrasts the main drawbacks of silica-based packings such as their relative thermal and chemical instability with excellent stability of metal oxides. The paper concerns mainly ZrO2, TiO 2 and Al2O3. Methods of preparation of spherical particles for HPLC are described. Surface chemistry of the oxides is, however, very different from that of silica. Ability of the oxides to ion- and ligand exchange is discussed from a chromatographic point of view.

KW - Alumina

KW - Ion exchange

KW - Ligand exchange

KW - Reviews

KW - Silica

KW - Spherical particles

KW - Stationary phases, LC

KW - Titania

KW - Zirconia

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DO - 10.1016/j.chroma.2003.11.052

M3 - Review article

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AN - SCOPUS:0347899380

SN - 0021-9673

VL - 1028

SP - 1

EP - 30

JO - Journal of Chromatography A

JF - Journal of Chromatography A

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Part I. Chromatography using ultra-stable metal oxide-based stationary phases for HPLC

Abstract

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