Palladium-triethylborane-triggered direct and regioselective conversion of allylic alcohols to allyl phenyl sulfones?

Srivari Chandrasekhar, Vannada Jagadeshwar, Birudaraju Saritha, Cheryala Narsihmulu

Research output: Contribution to journalArticle

54 Scopus citations

Abstract

A combination of Pd(OAc)2 (5 mol %), PPh3 (10 mol %), and Et3B (200 mol %) promotes the formation of allyl phenyl sulfones from the allylic alcohols directly with excellent yields under mild conditions. The activation of an alcohol group is not necessary which is achieved in situ. The conjugated dienols also were equally effective for the said transformation.

Original languageEnglish (US)
Pages (from-to)6506-6507
Number of pages2
JournalJournal of Organic Chemistry
Volume70
Issue number16
DOIs
StatePublished - Aug 5 2005
Externally publishedYes

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