TY - JOUR
T1 - Palladium-triethylborane-triggered direct and regioselective conversion of allylic alcohols to allyl phenyl sulfones?
AU - Chandrasekhar, Srivari
AU - Jagadeshwar, Vannada
AU - Saritha, Birudaraju
AU - Narsihmulu, Cheryala
PY - 2005/8/5
Y1 - 2005/8/5
N2 - A combination of Pd(OAc)2 (5 mol %), PPh3 (10 mol %), and Et3B (200 mol %) promotes the formation of allyl phenyl sulfones from the allylic alcohols directly with excellent yields under mild conditions. The activation of an alcohol group is not necessary which is achieved in situ. The conjugated dienols also were equally effective for the said transformation.
AB - A combination of Pd(OAc)2 (5 mol %), PPh3 (10 mol %), and Et3B (200 mol %) promotes the formation of allyl phenyl sulfones from the allylic alcohols directly with excellent yields under mild conditions. The activation of an alcohol group is not necessary which is achieved in situ. The conjugated dienols also were equally effective for the said transformation.
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U2 - 10.1021/jo0505728
DO - 10.1021/jo0505728
M3 - Article
C2 - 16050718
AN - SCOPUS:23044447811
SN - 0022-3263
VL - 70
SP - 6506
EP - 6507
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 16
ER -