Oxygen sensor with solid-state CeO2-ZrO2-TiO 2 reference

Nafiseh Rajabbeigi; Bahman Elyassi; Abbas Ali Khodadadi; Shamsoddin Mohajerzadeh; Yadollah Mortazavi; Muhammad Sahimi

doi:10.1016/j.snb.2004.12.079

Oxygen sensor with solid-state CeO₂-ZrO₂-TiO ₂ reference

Nafiseh Rajabbeigi, Bahman Elyassi, Abbas Ali Khodadadi, Shamsoddin Mohajerzadeh, Yadollah Mortazavi, Muhammad Sahimi

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Development of an oxygen sensor for automotive applications with a solid-state reference is reported. Unlike conventional oxygen sensors used in monitoring exhaust gas emissions, in which one side of the sensor must be directly exposed to the air reference, the new sensor employs a ternary mixed oxide of CeO₂-ZrO₂-TiO₂ (hereafter referred to as CZT) as the reference. The sensor consists of YSZ electrolyte and CZT reference layers with platinum coating as electrodes. The response of the sensor was investigated in a gas mixture of 6 mol% CO (in He) and air at 400, 500 and 600 °C. At 400 °C, the sensor generates a wide hysteresis in the lean region, while at higher temperatures a narrower hysteresis occurs at λ = 1. The sensor also exhibits variations in the voltage, from about +300 mV in the rich region to about -250 mV in the lean region, an interesting behavior not observed in air-referenced structures.

Original language	English (US)
Pages (from-to)	341-345
Number of pages	5
Journal	Sensors and Actuators, B: Chemical
Volume	108
Issue number	1-2 SPEC. ISS.
DOIs	https://doi.org/10.1016/j.snb.2004.12.079
State	Published - Jul 22 2005
Externally published	Yes

Bibliographical note

Funding Information:
The first five authors gratefully acknowledge support of their work by the University of Tehran. The authors express their gratitude to Dr. Nolven Guilhaume of the Université Claude Bernard Lyon 1 for commenting on the XRD pattern, and to Mr. S. Kiani for performing the SEM analysis.

Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.

Keywords

Ceria-zirconia-titania
Oxygen sensor
Solid-state reference
YSZ

Publisher link

10.1016/j.snb.2004.12.079

Find It

Find It at U of M Libraries

Cite this

@article{092a10439aae40c3943467b9612c6d22,

title = "Oxygen sensor with solid-state CeO2-ZrO2-TiO 2 reference",

abstract = "Development of an oxygen sensor for automotive applications with a solid-state reference is reported. Unlike conventional oxygen sensors used in monitoring exhaust gas emissions, in which one side of the sensor must be directly exposed to the air reference, the new sensor employs a ternary mixed oxide of CeO2-ZrO2-TiO2 (hereafter referred to as CZT) as the reference. The sensor consists of YSZ electrolyte and CZT reference layers with platinum coating as electrodes. The response of the sensor was investigated in a gas mixture of 6 mol% CO (in He) and air at 400, 500 and 600 °C. At 400 °C, the sensor generates a wide hysteresis in the lean region, while at higher temperatures a narrower hysteresis occurs at λ = 1. The sensor also exhibits variations in the voltage, from about +300 mV in the rich region to about -250 mV in the lean region, an interesting behavior not observed in air-referenced structures.",

keywords = "Ceria-zirconia-titania, Oxygen sensor, Solid-state reference, YSZ",

author = "Nafiseh Rajabbeigi and Bahman Elyassi and Khodadadi, {Abbas Ali} and Shamsoddin Mohajerzadeh and Yadollah Mortazavi and Muhammad Sahimi",

note = "Funding Information: The first five authors gratefully acknowledge support of their work by the University of Tehran. The authors express their gratitude to Dr. Nolven Guilhaume of the Universit{\'e} Claude Bernard Lyon 1 for commenting on the XRD pattern, and to Mr. S. Kiani for performing the SEM analysis. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2005",

month = jul,

day = "22",

doi = "10.1016/j.snb.2004.12.079",

language = "English (US)",

volume = "108",

pages = "341--345",

journal = "Sensors and Actuators, B: Chemical",

issn = "0925-4005",

publisher = "Elsevier B.V.",

number = "1-2 SPEC. ISS.",

}

TY - JOUR

T1 - Oxygen sensor with solid-state CeO2-ZrO2-TiO 2 reference

AU - Rajabbeigi, Nafiseh

AU - Elyassi, Bahman

AU - Khodadadi, Abbas Ali

AU - Mohajerzadeh, Shamsoddin

AU - Mortazavi, Yadollah

AU - Sahimi, Muhammad

N1 - Funding Information: The first five authors gratefully acknowledge support of their work by the University of Tehran. The authors express their gratitude to Dr. Nolven Guilhaume of the Université Claude Bernard Lyon 1 for commenting on the XRD pattern, and to Mr. S. Kiani for performing the SEM analysis. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2005/7/22

Y1 - 2005/7/22

N2 - Development of an oxygen sensor for automotive applications with a solid-state reference is reported. Unlike conventional oxygen sensors used in monitoring exhaust gas emissions, in which one side of the sensor must be directly exposed to the air reference, the new sensor employs a ternary mixed oxide of CeO2-ZrO2-TiO2 (hereafter referred to as CZT) as the reference. The sensor consists of YSZ electrolyte and CZT reference layers with platinum coating as electrodes. The response of the sensor was investigated in a gas mixture of 6 mol% CO (in He) and air at 400, 500 and 600 °C. At 400 °C, the sensor generates a wide hysteresis in the lean region, while at higher temperatures a narrower hysteresis occurs at λ = 1. The sensor also exhibits variations in the voltage, from about +300 mV in the rich region to about -250 mV in the lean region, an interesting behavior not observed in air-referenced structures.

AB - Development of an oxygen sensor for automotive applications with a solid-state reference is reported. Unlike conventional oxygen sensors used in monitoring exhaust gas emissions, in which one side of the sensor must be directly exposed to the air reference, the new sensor employs a ternary mixed oxide of CeO2-ZrO2-TiO2 (hereafter referred to as CZT) as the reference. The sensor consists of YSZ electrolyte and CZT reference layers with platinum coating as electrodes. The response of the sensor was investigated in a gas mixture of 6 mol% CO (in He) and air at 400, 500 and 600 °C. At 400 °C, the sensor generates a wide hysteresis in the lean region, while at higher temperatures a narrower hysteresis occurs at λ = 1. The sensor also exhibits variations in the voltage, from about +300 mV in the rich region to about -250 mV in the lean region, an interesting behavior not observed in air-referenced structures.

KW - Ceria-zirconia-titania

KW - Oxygen sensor

KW - Solid-state reference

KW - YSZ

UR - http://www.scopus.com/inward/record.url?scp=19744377406&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=19744377406&partnerID=8YFLogxK

U2 - 10.1016/j.snb.2004.12.079

DO - 10.1016/j.snb.2004.12.079

M3 - Article

AN - SCOPUS:19744377406

SN - 0925-4005

VL - 108

SP - 341

EP - 345

JO - Sensors and Actuators, B: Chemical

JF - Sensors and Actuators, B: Chemical

IS - 1-2 SPEC. ISS.

ER -