Oxidative decarboxylation of benzilic acid by a biomimetic iron(II) Complex: Evidence for an iron(IV)-oxo-hydroxo oxidant from O 2

Sayantan Paria; Lawrence Que; Tapan Kanti Paine

doi:10.1002/anie.201103971

Oxidative decarboxylation of benzilic acid by a biomimetic iron(II) Complex: Evidence for an iron(IV)-oxo-hydroxo oxidant from O ₂

Sayantan Paria
, Lawrence Que
, Tapan Kanti Paine

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

O ₂-dependent transformation: An iron(II)-benzilate complex of a tridentate N3 donor ligand reacts with O ₂ to undergo oxidative decarboxylation. Cyclohexene is selectively converted into cis-cyclohexane-1,2- diol in the reaction.

Original language	English (US)
Pages (from-to)	11129-11132
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	47
DOIs	https://doi.org/10.1002/anie.201103971
State	Published - Nov 18 2011

Keywords

benzilic acid
bioinorganic chemistry
cis-dihydroxylation
iron
oxidative decarboxylation

Publisher link

10.1002/anie.201103971

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title = "Oxidative decarboxylation of benzilic acid by a biomimetic iron(II) Complex: Evidence for an iron(IV)-oxo-hydroxo oxidant from O 2",

abstract = "O 2-dependent transformation: An iron(II)-benzilate complex of a tridentate N3 donor ligand reacts with O 2 to undergo oxidative decarboxylation. Cyclohexene is selectively converted into cis-cyclohexane-1,2- diol in the reaction.",

keywords = "benzilic acid, bioinorganic chemistry, cis-dihydroxylation, iron, oxidative decarboxylation",

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AU - Paine, Tapan Kanti

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KW - benzilic acid

KW - bioinorganic chemistry

KW - cis-dihydroxylation

KW - iron

KW - oxidative decarboxylation

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