Oxidation reactivity channels for 2-(pyridin-2-yl)-N,N-diphenylacetamides

Sylvie Pailloux; Iris Binyamin; Lorraine M. Deck; Brian M. Rapko; Benjamin P. Hay; Eileen N. Duesler; Robert T. Paine

doi:10.1021/jo701408y

Oxidation reactivity channels for 2-(pyridin-2-yl)-N,N-diphenylacetamides

Sylvie Pailloux, Iris Binyamin, Lorraine M. Deck, Brian M. Rapko, Benjamin P. Hay, Eileen N. Duesler, Robert T. Paine

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

(Chemical Equation Presented) Synthetic routes to 2-(pyridin-2-yl)-N,N- diphenylacetamide and 2-(6-methylpyridin-2-yl)-N,N-diphenylacetamide are described along with results from the chemical oxidation of these compounds with peracetic acid, m-chloroperbenzoic acid, and OXONE. In each case, oxidations generate four products in varying amounts depending on the oxidant and reaction conditions. Each product has been characterized by spectroscopic methods and the molecular structures of several of the new compounds have been confirmed by X-ray crystallography.

Original language	English (US)
Pages (from-to)	9195-9202
Number of pages	8
Journal	Journal of Organic Chemistry
Volume	72
Issue number	24
DOIs	https://doi.org/10.1021/jo701408y
State	Published - Nov 23 2007

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title = "Oxidation reactivity channels for 2-(pyridin-2-yl)-N,N-diphenylacetamides",

abstract = "(Chemical Equation Presented) Synthetic routes to 2-(pyridin-2-yl)-N,N- diphenylacetamide and 2-(6-methylpyridin-2-yl)-N,N-diphenylacetamide are described along with results from the chemical oxidation of these compounds with peracetic acid, m-chloroperbenzoic acid, and OXONE. In each case, oxidations generate four products in varying amounts depending on the oxidant and reaction conditions. Each product has been characterized by spectroscopic methods and the molecular structures of several of the new compounds have been confirmed by X-ray crystallography.",

author = "Sylvie Pailloux and Iris Binyamin and Deck, {Lorraine M.} and Rapko, {Brian M.} and Hay, {Benjamin P.} and Duesler, {Eileen N.} and Paine, {Robert T.}",

year = "2007",

month = nov,

day = "23",

doi = "10.1021/jo701408y",

language = "English (US)",

volume = "72",

pages = "9195--9202",

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T1 - Oxidation reactivity channels for 2-(pyridin-2-yl)-N,N-diphenylacetamides

AU - Pailloux, Sylvie

AU - Binyamin, Iris

AU - Deck, Lorraine M.

AU - Rapko, Brian M.

AU - Hay, Benjamin P.

AU - Duesler, Eileen N.

AU - Paine, Robert T.

PY - 2007/11/23

Y1 - 2007/11/23

N2 - (Chemical Equation Presented) Synthetic routes to 2-(pyridin-2-yl)-N,N- diphenylacetamide and 2-(6-methylpyridin-2-yl)-N,N-diphenylacetamide are described along with results from the chemical oxidation of these compounds with peracetic acid, m-chloroperbenzoic acid, and OXONE. In each case, oxidations generate four products in varying amounts depending on the oxidant and reaction conditions. Each product has been characterized by spectroscopic methods and the molecular structures of several of the new compounds have been confirmed by X-ray crystallography.

AB - (Chemical Equation Presented) Synthetic routes to 2-(pyridin-2-yl)-N,N- diphenylacetamide and 2-(6-methylpyridin-2-yl)-N,N-diphenylacetamide are described along with results from the chemical oxidation of these compounds with peracetic acid, m-chloroperbenzoic acid, and OXONE. In each case, oxidations generate four products in varying amounts depending on the oxidant and reaction conditions. Each product has been characterized by spectroscopic methods and the molecular structures of several of the new compounds have been confirmed by X-ray crystallography.

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 24

ER -

Oxidation reactivity channels for 2-(pyridin-2-yl)-N,N-diphenylacetamides

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