Oxidation of Ru(dppe)(CO)3 with o- and p-quinones. Crystal structure of Ru[C(O)OC6H2(C4H9) 2O](dppe)(CO)2

Amy L. Jorgenson; Robert A. Nadeau; Victor G. Young; Wayne L. Gladfelter

doi:10.1016/S0022-328X(98)00537-3

Oxidation of Ru(dppe)(CO)₃ with o- and p-quinones. Crystal structure of Ru[C(O)OC₆H₂(C₄H₉) ₂O](dppe)(CO)₂

Amy L. Jorgenson, Robert A. Nadeau, Victor G. Young, Wayne L. Gladfelter

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The oxidation of Ru(dppe)(CO)₃ with various o- and p-quinones is described. Reaction with 3,5-di-t-butyl-o-benzoquinone yielded a metallacyclic complex which crystallizes in the monoclinic space group P2₁/c with a = 21.8388 (1), b = 12.0734 (1), c = 17.6173 (3) Å, β = 105.549 (1), and Z = 4. The complex exhibited slightly distorted octahedral geometry and contained a puckered metallacyclic ring resulting from the formal addition of the o-quinone moiety across the Ru-C bond of a metal carbonyl. Reaction of this quinone adduct with an alkylamine produced a known bis(carbamoyl) complex, Ru(dppe)(CO)₂[C(O)NHR]₂. The reaction of Ru(dppe)(CO)₃ with p-quinones generated unidentified oxidation products which exhibited a similar reactivity with amines to form bis(carbamoyl) complexes.

Original language	English (US)
Pages (from-to)	1-6
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	563
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(98)00537-3
State	Published - Jul 30 1998

Bibliographical note

Funding Information:
This research was funded by a grant from the National Science Foundation (CHE-9223433).

Keywords

Crystal structure
Oxidation
Quinones

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10.1016/S0022-328X(98)00537-3

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@article{4a1382dd49604946a3c26e8f9d87d1ec,

title = "Oxidation of Ru(dppe)(CO)3 with o- and p-quinones. Crystal structure of Ru[C(O)OC6H2(C4H9) 2O](dppe)(CO)2",

abstract = "The oxidation of Ru(dppe)(CO)3 with various o- and p-quinones is described. Reaction with 3,5-di-t-butyl-o-benzoquinone yielded a metallacyclic complex which crystallizes in the monoclinic space group P21/c with a = 21.8388 (1), b = 12.0734 (1), c = 17.6173 (3) {\AA}, β = 105.549 (1), and Z = 4. The complex exhibited slightly distorted octahedral geometry and contained a puckered metallacyclic ring resulting from the formal addition of the o-quinone moiety across the Ru-C bond of a metal carbonyl. Reaction of this quinone adduct with an alkylamine produced a known bis(carbamoyl) complex, Ru(dppe)(CO)2[C(O)NHR]2. The reaction of Ru(dppe)(CO)3 with p-quinones generated unidentified oxidation products which exhibited a similar reactivity with amines to form bis(carbamoyl) complexes.",

keywords = "Crystal structure, Oxidation, Quinones",

author = "Jorgenson, {Amy L.} and Nadeau, {Robert A.} and Young, {Victor G.} and Gladfelter, {Wayne L.}",

note = "Funding Information: This research was funded by a grant from the National Science Foundation (CHE-9223433). ",

year = "1998",

month = jul,

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doi = "10.1016/S0022-328X(98)00537-3",

language = "English (US)",

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T1 - Oxidation of Ru(dppe)(CO)3 with o- and p-quinones. Crystal structure of Ru[C(O)OC6H2(C4H9) 2O](dppe)(CO)2

AU - Jorgenson, Amy L.

AU - Nadeau, Robert A.

AU - Young, Victor G.

AU - Gladfelter, Wayne L.

N1 - Funding Information: This research was funded by a grant from the National Science Foundation (CHE-9223433).

PY - 1998/7/30

Y1 - 1998/7/30

N2 - The oxidation of Ru(dppe)(CO)3 with various o- and p-quinones is described. Reaction with 3,5-di-t-butyl-o-benzoquinone yielded a metallacyclic complex which crystallizes in the monoclinic space group P21/c with a = 21.8388 (1), b = 12.0734 (1), c = 17.6173 (3) Å, β = 105.549 (1), and Z = 4. The complex exhibited slightly distorted octahedral geometry and contained a puckered metallacyclic ring resulting from the formal addition of the o-quinone moiety across the Ru-C bond of a metal carbonyl. Reaction of this quinone adduct with an alkylamine produced a known bis(carbamoyl) complex, Ru(dppe)(CO)2[C(O)NHR]2. The reaction of Ru(dppe)(CO)3 with p-quinones generated unidentified oxidation products which exhibited a similar reactivity with amines to form bis(carbamoyl) complexes.

AB - The oxidation of Ru(dppe)(CO)3 with various o- and p-quinones is described. Reaction with 3,5-di-t-butyl-o-benzoquinone yielded a metallacyclic complex which crystallizes in the monoclinic space group P21/c with a = 21.8388 (1), b = 12.0734 (1), c = 17.6173 (3) Å, β = 105.549 (1), and Z = 4. The complex exhibited slightly distorted octahedral geometry and contained a puckered metallacyclic ring resulting from the formal addition of the o-quinone moiety across the Ru-C bond of a metal carbonyl. Reaction of this quinone adduct with an alkylamine produced a known bis(carbamoyl) complex, Ru(dppe)(CO)2[C(O)NHR]2. The reaction of Ru(dppe)(CO)3 with p-quinones generated unidentified oxidation products which exhibited a similar reactivity with amines to form bis(carbamoyl) complexes.

KW - Crystal structure

KW - Oxidation

KW - Quinones

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