Oxidation of methyl to methoxy on oxidized Cu/SiO2

M. D. Driessen, V. H. Grassian

Research output: Contribution to journalArticle

12 Scopus citations

Abstract

The room-temperature adsorption of methyl iodide on an oxidized copper silica catalyst has been investigated using FT-IR spectroscopy. After reaction of methyl iodide with an oxidized Cu/SiO2 catalyst, oxygenated hydrocarbons including methoxy and bidentate formate are present on the copper surface. The data suggest that the carbon-iodine bond in adsorbed methyl iodide dissociates on the oxidized copper particles, methyl groups then react with surface oxygen to form adsorbed methoxide and formate. The reactions of adsorbed methoxide and formate were monitored in the temperature range extending from approximately 300 to 600 K.

Original languageEnglish (US)
Pages (from-to)16519-16522
Number of pages4
JournalJournal of physical chemistry
Volume99
Issue number45
StatePublished - Dec 1 1995

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