TY - JOUR
T1 - Organoosmium Oxides
T2 - Efficient Syntheses and Structures
AU - Herrmann, Wolfgang A.
AU - Eder, Stefan J.
AU - Kiprof, Paul
AU - Rypdal, Kristin
AU - Watzlowik, Petra
PY - 1990/12
Y1 - 1990/12
N2 - Not only the hitherto simplest alkylosmium oxide, Me4OsO, which is stable in the gas phase, and whose structure (figure on the right) can elucidated by electron diffraction analysis, but also the thermolabile Et4OsO and a mixed alkylated derivative could be prepared good yields. In addition, the structurally novel trimer [{(py)OsO2Me2}3] with planar Os3O3 six‐membered ring is reported. (Figure Presented.)
AB - Not only the hitherto simplest alkylosmium oxide, Me4OsO, which is stable in the gas phase, and whose structure (figure on the right) can elucidated by electron diffraction analysis, but also the thermolabile Et4OsO and a mixed alkylated derivative could be prepared good yields. In addition, the structurally novel trimer [{(py)OsO2Me2}3] with planar Os3O3 six‐membered ring is reported. (Figure Presented.)
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U2 - 10.1002/anie.199014451
DO - 10.1002/anie.199014451
M3 - Article
AN - SCOPUS:33748211684
SN - 1433-7851
VL - 29
SP - 1445
EP - 1448
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 12
ER -