Organoiodine(V) reagents in organic synthesis

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244 Scopus citations

Abstract

Organohypervalent iodine reagents have attracted significant recent interest as versatile and environmentally benign oxidants with numerous applications in organic synthesis. This Perspective summarizes synthetic applications of hypervalent iodine(V) reagents: 2-iodoxybenzoic acid (IBX), Dess-Martin periodinane (DMP), pseudocyclic iodylarenes, and their recyclable polymer-supported analogues. Recent advances in the development of new catalytic systems based on the generation of hypervalent iodine species in situ are also overviewed.(Figure Presented)

Original languageEnglish (US)
Pages (from-to)1185-1197
Number of pages13
JournalJournal of Organic Chemistry
Volume76
Issue number5
DOIs
StatePublished - Mar 4 2011

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