One-pot synthesis of 5-(Ethoxymethyl)furfural from glucose using Sn-BEA and Amberlyst catalysts

Christopher M. Lew; Nafiseh Rajabbeigi; Michael Tsapatsis

doi:10.1021/ie2025536

One-pot synthesis of 5-(Ethoxymethyl)furfural from glucose using Sn-BEA and Amberlyst catalysts

Christopher M. Lew, Nafiseh Rajabbeigi, Michael Tsapatsis

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

176 Scopus citations

Abstract

5-(Ethoxymethyl)furfural (EMF) was produced from glucose in ethanol in a single reactor at 90 °C. The reaction proceeds via the isomerization of glucose to fructose with zeolite Sn-Beta, a Lewis acid catalyst. Fructose is converted to 5-(hydroxymethyl)furfural, which is then etherified to EMF using a Brønsted acid catalyst, Amberlyst 131. An EMF yield of 31% was achieved.

Original language	English (US)
Pages (from-to)	5364-5366
Number of pages	3
Journal	Industrial and Engineering Chemistry Research
Volume	51
Issue number	14
DOIs	https://doi.org/10.1021/ie2025536
State	Published - Apr 11 2012

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10.1021/ie2025536

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abstract = "5-(Ethoxymethyl)furfural (EMF) was produced from glucose in ethanol in a single reactor at 90 °C. The reaction proceeds via the isomerization of glucose to fructose with zeolite Sn-Beta, a Lewis acid catalyst. Fructose is converted to 5-(hydroxymethyl)furfural, which is then etherified to EMF using a Br{\o}nsted acid catalyst, Amberlyst 131. An EMF yield of 31% was achieved.",

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AU - Rajabbeigi, Nafiseh

AU - Tsapatsis, Michael

PY - 2012/4/11

Y1 - 2012/4/11

N2 - 5-(Ethoxymethyl)furfural (EMF) was produced from glucose in ethanol in a single reactor at 90 °C. The reaction proceeds via the isomerization of glucose to fructose with zeolite Sn-Beta, a Lewis acid catalyst. Fructose is converted to 5-(hydroxymethyl)furfural, which is then etherified to EMF using a Brønsted acid catalyst, Amberlyst 131. An EMF yield of 31% was achieved.

AB - 5-(Ethoxymethyl)furfural (EMF) was produced from glucose in ethanol in a single reactor at 90 °C. The reaction proceeds via the isomerization of glucose to fructose with zeolite Sn-Beta, a Lewis acid catalyst. Fructose is converted to 5-(hydroxymethyl)furfural, which is then etherified to EMF using a Brønsted acid catalyst, Amberlyst 131. An EMF yield of 31% was achieved.

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One-pot synthesis of 5-(Ethoxymethyl)furfural from glucose using Sn-BEA and Amberlyst catalysts

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