One-dimensional Cu(II) coordination polymers: Tuning the structure by modulating the "carboxylate arm" lengths of polycarboxylate ligands

Ramadan Abuhmaiera; Yanhua Lan; Ayuk M. Ako; George E. Kostakis; Andreas Mavrantonakis; Wim Klopper; Rodolphe Clérac; Christopher E. Anson; Annie K. Powell

doi:10.1039/b820834d

One-dimensional Cu(II) coordination polymers: Tuning the structure by modulating the "carboxylate arm" lengths of polycarboxylate ligands

Ramadan Abuhmaiera
, Yanhua Lan
, Ayuk M. Ako
, George E. Kostakis
, Andreas Mavrantonakis
, Wim Klopper
, Rodolphe Clérac
, Christopher E. Anson
, Annie K. Powell

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

To understand the influence of the ligand on crystal growth, two new polycarboxylate ligands, 2-(carboxyphenyl)iminoacetic propanoic acid (H ₃cpiap) and 2-(carboxyphenyl)iminodipropanoic acid (H ₃cpidp), have been synthesized. The reaction of each with Cu(NO ₃)₂·3H₂O under similar reaction conditions yields two 1D coordination polymers {[Cu₃(cpiap) ₂(H₂O)₃](-H₂O)}_n· 7nH₂O (1) and [Cu(H₂cpidp)₂(H ₂O)₂]_n·4nH₂O (2), respectively. A T5(2) 1D water tape constructed from an edge-sharing cyclic pentamer has been observed in compound 1, in which the water chains interact with the 1D coordination polymer chains to form a 3D supramolecular binodal (5,8)-network through hydrogen-bonding interactions.

Original language	English (US)
Pages (from-to)	1089-1096
Number of pages	8
Journal	CrystEngComm
Volume	11
Issue number	6
DOIs	https://doi.org/10.1039/b820834d
State	Published - 2009

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title = "One-dimensional Cu(II) coordination polymers: Tuning the structure by modulating the {"}carboxylate arm{"} lengths of polycarboxylate ligands",

abstract = "To understand the influence of the ligand on crystal growth, two new polycarboxylate ligands, 2-(carboxyphenyl)iminoacetic propanoic acid (H 3cpiap) and 2-(carboxyphenyl)iminodipropanoic acid (H 3cpidp), have been synthesized. The reaction of each with Cu(NO 3)2·3H2O under similar reaction conditions yields two 1D coordination polymers \{[Cu3(cpiap) 2(H2O)3](-H2O)\}n· 7nH2O (1) and [Cu(H2cpidp)2(H 2O)2]n·4nH2O (2), respectively. A T5(2) 1D water tape constructed from an edge-sharing cyclic pentamer has been observed in compound 1, in which the water chains interact with the 1D coordination polymer chains to form a 3D supramolecular binodal (5,8)-network through hydrogen-bonding interactions.",

author = "Ramadan Abuhmaiera and Yanhua Lan and Ako, \{Ayuk M.\} and Kostakis, \{George E.\} and Andreas Mavrantonakis and Wim Klopper and Rodolphe Cl{\'e}rac and Anson, \{Christopher E.\} and Powell, \{Annie K.\}",

year = "2009",

doi = "10.1039/b820834d",

language = "English (US)",

volume = "11",

pages = "1089--1096",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "6",

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TY - JOUR

T1 - One-dimensional Cu(II) coordination polymers

T2 - Tuning the structure by modulating the "carboxylate arm" lengths of polycarboxylate ligands

AU - Abuhmaiera, Ramadan

AU - Lan, Yanhua

AU - Ako, Ayuk M.

AU - Kostakis, George E.

AU - Mavrantonakis, Andreas

AU - Klopper, Wim

AU - Clérac, Rodolphe

AU - Anson, Christopher E.

AU - Powell, Annie K.

PY - 2009

Y1 - 2009

N2 - To understand the influence of the ligand on crystal growth, two new polycarboxylate ligands, 2-(carboxyphenyl)iminoacetic propanoic acid (H 3cpiap) and 2-(carboxyphenyl)iminodipropanoic acid (H 3cpidp), have been synthesized. The reaction of each with Cu(NO 3)2·3H2O under similar reaction conditions yields two 1D coordination polymers {[Cu3(cpiap) 2(H2O)3](-H2O)}n· 7nH2O (1) and [Cu(H2cpidp)2(H 2O)2]n·4nH2O (2), respectively. A T5(2) 1D water tape constructed from an edge-sharing cyclic pentamer has been observed in compound 1, in which the water chains interact with the 1D coordination polymer chains to form a 3D supramolecular binodal (5,8)-network through hydrogen-bonding interactions.

AB - To understand the influence of the ligand on crystal growth, two new polycarboxylate ligands, 2-(carboxyphenyl)iminoacetic propanoic acid (H 3cpiap) and 2-(carboxyphenyl)iminodipropanoic acid (H 3cpidp), have been synthesized. The reaction of each with Cu(NO 3)2·3H2O under similar reaction conditions yields two 1D coordination polymers {[Cu3(cpiap) 2(H2O)3](-H2O)}n· 7nH2O (1) and [Cu(H2cpidp)2(H 2O)2]n·4nH2O (2), respectively. A T5(2) 1D water tape constructed from an edge-sharing cyclic pentamer has been observed in compound 1, in which the water chains interact with the 1D coordination polymer chains to form a 3D supramolecular binodal (5,8)-network through hydrogen-bonding interactions.

UR - https://www.scopus.com/pages/publications/69249122962

UR - https://www.scopus.com/pages/publications/69249122962#tab=citedBy

U2 - 10.1039/b820834d

DO - 10.1039/b820834d

M3 - Article

AN - SCOPUS:69249122962

SN - 1466-8033

VL - 11

SP - 1089

EP - 1096

JO - CrystEngComm

JF - CrystEngComm

IS - 6

ER -

One-dimensional Cu(II) coordination polymers: Tuning the structure by modulating the "carboxylate arm" lengths of polycarboxylate ligands

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