On the Suppression-of-Junction-Fluctuations Parameter in Flory's Network Theory

M. Gottlieb, C. W. Macosko

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

The concept of suppression of junction fluctuations in polymer networks is quantified by means of κ in Flory's recent network elasticity theory. The same concept is also measured by the h parameter in Dossin and Graessley's expression for the small-strain modulus. In this work an analytical relationship between these two physically related parameters is obtained for the case of a perfect, incompressible, unswollen network.

Original languageEnglish (US)
Pages (from-to)535-537
Number of pages3
JournalMacromolecules
Volume15
Issue number2
DOIs
StatePublished - 1982

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