Novel trifluoroethyliodonium salts from cyclic enaminones and their thermal decomposition

Ioannis Papoutsis, Spyros Spyroudis, Anastasios Varvoglis, Jeffrey A. Callies, Viktor Zhdankin

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

Upon reaction of 1-[hydroxy(tosyloxy)iodo]-2,2,2-trifluoroethane with cyclic enaminones, stable iodonium tosylates are obtained. Their mild thermolysis provides iodoenaminones and 2,2,2-trifluoroethyl tosylate.

Original languageEnglish (US)
Pages (from-to)8401-8404
Number of pages4
JournalTetrahedron Letters
Volume38
Issue number48
DOIs
StatePublished - Dec 1 1997

Bibliographical note

Funding Information:
Acknowledgment. This work was partially supported by a research grant from the National Science Foundation (NSF/CHE-9505868) in USA.

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