Novel reactivity of side-on (disulfido)dicopper complexes supported by bi- and tridentate nitrogen donors: Impact of axial coordination

Itsik Bar-Nahum; John T. York; Victor G. Young; William B. Tolman

doi:10.1002/anie.200704690

Novel reactivity of side-on (disulfido)dicopper complexes supported by bi- and tridentate nitrogen donors: Impact of axial coordination

Itsik Bar-Nahum, John T. York, Victor G. Young, William B. Tolman

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

(Figure Presented) What a difference a ligand makes: A comparison of the reactivity of the two complexes shown (Cu green, S yellow, N blue, O red, F pink, C gray) has revealed new redox processes previously unseen for copper-sulfur complexes. Furthermore, intriguing supporting-ligand effects on the properties of (disulfido)dicopper cores are uncovered.

Original language	English (US)
Pages (from-to)	533-536
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	3
DOIs	https://doi.org/10.1002/anie.200704690
State	Published - 2008

Keywords

Copper
Disulfide
Oxidation
Sulfur

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10.1002/anie.200704690

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AU - York, John T.

AU - Young, Victor G.

AU - Tolman, William B.

PY - 2008

Y1 - 2008

N2 - (Figure Presented) What a difference a ligand makes: A comparison of the reactivity of the two complexes shown (Cu green, S yellow, N blue, O red, F pink, C gray) has revealed new redox processes previously unseen for copper-sulfur complexes. Furthermore, intriguing supporting-ligand effects on the properties of (disulfido)dicopper cores are uncovered.

AB - (Figure Presented) What a difference a ligand makes: A comparison of the reactivity of the two complexes shown (Cu green, S yellow, N blue, O red, F pink, C gray) has revealed new redox processes previously unseen for copper-sulfur complexes. Furthermore, intriguing supporting-ligand effects on the properties of (disulfido)dicopper cores are uncovered.

KW - Copper

KW - Disulfide

KW - Oxidation

KW - Sulfur

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Novel reactivity of side-on (disulfido)dicopper complexes supported by bi- and tridentate nitrogen donors: Impact of axial coordination

Abstract

Keywords

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