Novel reactivity of side-on (disulfido)dicopper complexes supported by bi- and tridentate nitrogen donors: Impact of axial coordination

Itsik Bar-Nahum, John T. York, Victor G. Young, William B. Tolman

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

(Figure Presented) What a difference a ligand makes: A comparison of the reactivity of the two complexes shown (Cu green, S yellow, N blue, O red, F pink, C gray) has revealed new redox processes previously unseen for copper-sulfur complexes. Furthermore, intriguing supporting-ligand effects on the properties of (disulfido)dicopper cores are uncovered.

Original languageEnglish (US)
Pages (from-to)533-536
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number3
DOIs
StatePublished - 2008

Keywords

  • Copper
  • Disulfide
  • Oxidation
  • Sulfur

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