Novel methodologies for the synthesis of functionalized lipophilic carboranes

Subash C. Jonnalagadda; Steven R. Verga; Parth D. Patel; A. V. Reddy; T. Srinivas; Patricia M Scott; Venkatram R Mereddy

doi:10.1002/aoc.1598

Novel methodologies for the synthesis of functionalized lipophilic carboranes

Subash C. Jonnalagadda, Steven R. Verga, Parth D. Patel, A. V. Reddy, T. Srinivas, Patricia M Scott, Venkatram R Mereddy

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Novel synthetic protocols for the synthesis of lipophilic carboranes were developed utilizing two C-C bond forming reactions, namely Baylis-Hillman and enynedioate cycloaddition reactions. Some of these carboranes were converted into further functionalized carboranes via nucleophilic allylic isomerization.

Original language	English (US)
Pages (from-to)	294-300
Number of pages	7
Journal	Applied Organometallic Chemistry
Volume	24
Issue number	4
DOIs	https://doi.org/10.1002/aoc.1598
State	Published - Apr 2010

Keywords

Baylis Hillman reaction
Carboranes
Cholesterol
Lipophilic carboranes
Low density lipoprotein

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10.1002/aoc.1598

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abstract = "Novel synthetic protocols for the synthesis of lipophilic carboranes were developed utilizing two C-C bond forming reactions, namely Baylis-Hillman and enynedioate cycloaddition reactions. Some of these carboranes were converted into further functionalized carboranes via nucleophilic allylic isomerization.",

keywords = "Baylis Hillman reaction, Carboranes, Cholesterol, Lipophilic carboranes, Low density lipoprotein",

author = "Jonnalagadda, \{Subash C.\} and Verga, \{Steven R.\} and Patel, \{Parth D.\} and Reddy, \{A. V.\} and T. Srinivas and Scott, \{Patricia M\} and Mereddy, \{Venkatram R\}",

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AU - Jonnalagadda, Subash C.

AU - Verga, Steven R.

AU - Patel, Parth D.

AU - Reddy, A. V.

AU - Srinivas, T.

AU - Scott, Patricia M

AU - Mereddy, Venkatram R

PY - 2010/4

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AB - Novel synthetic protocols for the synthesis of lipophilic carboranes were developed utilizing two C-C bond forming reactions, namely Baylis-Hillman and enynedioate cycloaddition reactions. Some of these carboranes were converted into further functionalized carboranes via nucleophilic allylic isomerization.

KW - Baylis Hillman reaction

KW - Carboranes

KW - Cholesterol

KW - Lipophilic carboranes

KW - Low density lipoprotein

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JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 4

ER -

Novel methodologies for the synthesis of functionalized lipophilic carboranes

Abstract

Keywords

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