Novel method for determining ²³⁴U-²³⁸U ages of Devils Hole 2 cave calcite (Nevada)

Uranium-uranium (234U-238U) disequilibrium dating can determine the age of secondary carbonates over greater time intervals than the well-established 230Th-234U dating method. Yet it is rarely applied due to unknowns in the initial δ234U (δ234Ui) value, which result in significant age uncertainties. In order to understand the δ234Ui in Devils Hole 2 cave, Nevada, we have determined 110 δ234Ui values from phreatic calcite using 230Th-234U disequilibrium dating. The sampled calcite was deposited in Devils Hole 2 between 4 and 590 ka, providing a long-term look at δ234Ui variability over time. We then performed multi-linear regression among the δ234Ui values and correlative δ18O and δ13C values. The regression can be used to estimate the δ234Ui value of Devils Hole calcite based upon its measured δ18O and δ13C values. Using this approach and the measured present-day δ234U values of Devils Hole 2 calcite, we calculated 110 independent 234U-238U ages. In addition, we used newly measured δ18O, δ13C, and present-day δ234U values to calculate 10 234U-238U ages that range between 676 and 731 ka, thus allowing us to extend the Devils Hole chronology beyond the 230Th-234U-dated chronology while maintaining an age precision of ∼2 %. Our results indicate that calcite deposition at Devils Hole 2 cave began no later than 736 ± 11 kyr ago. The novel method presented here may be applied to future speleothem studies in similar hydrogeological settings, given appropriate calibration studies.