Abstract
We conduct a numerical study of the dynamic behavior of a dense hard-sphere fluid by deriving and integrating a set of Langevin equations. The statics of the system is described by a free-energy functional of the Ramakrishnan-Yussouff form. We find that the system exhibits glassy behavior as evidenced through a stretched exponential decay and a two-stage relaxation of the density correlation function. The characteristic times grow with increasing density according to the Vogel-Fulcher law. The wave-number dependence of the kinetics is extensively explored. The connection of our results with experiment, mode-coupling theory, and molecular-dynamics results is discussed.
Original language | English (US) |
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Pages (from-to) | 1787-1798 |
Number of pages | 12 |
Journal | Physical Review E |
Volume | 48 |
Issue number | 3 |
DOIs | |
State | Published - 1993 |