TY - JOUR

T1 - Non-Boltzmann vibrational energy distributions and coupling to dissociation rate

AU - Singh, Narendra

AU - Schwartzentruber, Thomas

PY - 2020/6/14

Y1 - 2020/6/14

N2 - In this article, we propose a generalized model for nonequilibrium vibrational energy distribution functions. The model can be used, in place of equilibrium (Boltzmann) distribution functions, when deriving reaction rate constants for high-temperature nonequilibrium flows. The distribution model is derived based on the recent ab initio calculations, carried out using potential energy surfaces developed using accurate computational quantum chemistry techniques for the purpose of studying air chemistry at high temperatures. Immediately behind a strong shock wave, the vibrational energy distribution is non-Boltzmann. Specifically, as the gas internal energy rapidly excites to a high temperature, overpopulation of the high-energy tail (relative to a corresponding Boltzmann distribution) is observed in ab initio simulations. As the gas excites further and begins to dissociate, a depletion of the high-energy tail is observed, during a time-invariant quasi-steady state. Since the probability of dissociation is exponentially related to the vibrational energy of the dissociating molecule, the overall dissociation rate is sensitive to the populations of these high vibrational energy states. The non-Boltzmann effects captured by the new model either enhance or reduce the dissociation rate relative to that obtained assuming a Boltzmann distribution. This article proposes a simple model that is demonstrated to reproduce these non-Boltzmann effects quantitatively when compared to ab initio simulations.

AB - In this article, we propose a generalized model for nonequilibrium vibrational energy distribution functions. The model can be used, in place of equilibrium (Boltzmann) distribution functions, when deriving reaction rate constants for high-temperature nonequilibrium flows. The distribution model is derived based on the recent ab initio calculations, carried out using potential energy surfaces developed using accurate computational quantum chemistry techniques for the purpose of studying air chemistry at high temperatures. Immediately behind a strong shock wave, the vibrational energy distribution is non-Boltzmann. Specifically, as the gas internal energy rapidly excites to a high temperature, overpopulation of the high-energy tail (relative to a corresponding Boltzmann distribution) is observed in ab initio simulations. As the gas excites further and begins to dissociate, a depletion of the high-energy tail is observed, during a time-invariant quasi-steady state. Since the probability of dissociation is exponentially related to the vibrational energy of the dissociating molecule, the overall dissociation rate is sensitive to the populations of these high vibrational energy states. The non-Boltzmann effects captured by the new model either enhance or reduce the dissociation rate relative to that obtained assuming a Boltzmann distribution. This article proposes a simple model that is demonstrated to reproduce these non-Boltzmann effects quantitatively when compared to ab initio simulations.

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U2 - 10.1063/1.5142732

DO - 10.1063/1.5142732

M3 - Article

C2 - 32534520

AN - SCOPUS:85086622022

SN - 0021-9606

VL - 152

SP - 224301

JO - The Journal of chemical physics

JF - The Journal of chemical physics

IS - 22

ER -