Nitrogen-Nitrogen Double-Bond Scission of Azoarenes by Ru3(NAr)(CO)10. Struture and Catalytic Activity of H2Ru3(NAr)2(CO)8

Joanne A. Smieja, John E. Gozum, Wayne L. Gladfelter

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

Azoarenes react with Ru3(NArXCO)10 giving Ru3(NAr)(NAr‘XCO)9 in high yields. These bis(imido) clusters react with H2 to give H2Ru3(NAr)(NAr)(CO)8, which can be used to catalyze the hydrogenation of olefins.

Original languageEnglish (US)
Pages (from-to)2154-2155
Number of pages2
JournalOrganometallics
Volume5
Issue number10
DOIs
StatePublished - Jan 1 1986

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