(Nitrito-O,O')bis(triphenylphosphine)-copper(I), (PPh3)2Cu(NO2-O,O').

J. A. Halfen; William B Tolman

doi:10.1107/s0108270194008991

(Nitrito-O,O')bis(triphenylphosphine)-copper(I), (PPh3)2Cu(NO2-O,O').

J. A. Halfen, William B Tolman

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Symmetric binding of nitrite via both O atoms to CuI [Cu--O = 2.191 (4) A] was observed. The copper coordination geometry is significantly distorted from tetrahedral, as evidenced by the angles P--Cu--P [127.75 (7) degrees] and O--Cu--O [56.7 (2) degrees].

Original language	English (US)
Pages (from-to)	215-217
Number of pages	3
Journal	Acta crystallographica. Section C, Crystal structure communications
Volume	51 ( Pt 2)
DOIs	https://doi.org/10.1107/s0108270194008991
State	Published - Feb 15 1995

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title = "(Nitrito-O,O')bis(triphenylphosphine)-copper(I), (PPh3)2Cu(NO2-O,O').",

abstract = "Symmetric binding of nitrite via both O atoms to CuI [Cu--O = 2.191 (4) A] was observed. The copper coordination geometry is significantly distorted from tetrahedral, as evidenced by the angles P--Cu--P [127.75 (7) degrees] and O--Cu--O [56.7 (2) degrees].",

author = "Halfen, {J. A.} and Tolman, {William B}",

year = "1995",

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doi = "10.1107/s0108270194008991",

language = "English (US)",

volume = "51 ( Pt 2)",

pages = "215--217",

journal = "Acta crystallographica. Section C, Crystal structure communications",

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publisher = "International Union of Crystallography",

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T1 - (Nitrito-O,O')bis(triphenylphosphine)-copper(I), (PPh3)2Cu(NO2-O,O').

AU - Halfen, J. A.

AU - Tolman, William B

PY - 1995/2/15

Y1 - 1995/2/15

N2 - Symmetric binding of nitrite via both O atoms to CuI [Cu--O = 2.191 (4) A] was observed. The copper coordination geometry is significantly distorted from tetrahedral, as evidenced by the angles P--Cu--P [127.75 (7) degrees] and O--Cu--O [56.7 (2) degrees].

AB - Symmetric binding of nitrite via both O atoms to CuI [Cu--O = 2.191 (4) A] was observed. The copper coordination geometry is significantly distorted from tetrahedral, as evidenced by the angles P--Cu--P [127.75 (7) degrees] and O--Cu--O [56.7 (2) degrees].

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U2 - 10.1107/s0108270194008991

DO - 10.1107/s0108270194008991

M3 - Article

C2 - 7734085

AN - SCOPUS:0029644008

SN - 0108-2701

VL - 51 ( Pt 2)

SP - 215

EP - 217

JO - Acta crystallographica. Section C, Crystal structure communications

JF - Acta crystallographica. Section C, Crystal structure communications

ER -

(Nitrito-O,O')bis(triphenylphosphine)-copper(I), (PPh3)2Cu(NO2-O,O').

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