NEW VINYL ORGANOMETALLIC MONOMERS: SYNTHESIS AND POLYMERIZATION BEHAVIOR.

Marvin D. Rausch, David W. Macomber, Francis G. Fang, Charles U. Pittman, T. V. Jayaraman, Ralph D. Priester

Research output: Chapter in Book/Report/Conference proceedingConference contribution

3 Scopus citations

Abstract

In this work, ( eta **5-vinylcyclopentadienyl)tricarbonyl-manganese, ( eta **5-vinylcyclopentadienyl)dicarbonylnitrosylchromium,and 3-vinylbisfulvalenediiron were prepared. In each case, the synthetic route involved Friedel-Crafts acylation of the Cp-metal complex followed by hydride reduction of the acetyl carbonyl function to an alcohol, and dehydration. Polymerization studies of these monomers under free-radical of cationic initiation conditions are being studied and some results are discussed.

Original languageEnglish (US)
Title of host publicationPolymer Science and Technology
PublisherPlenum Press
Pages243-267
Number of pages25
ISBN (Print)0306414775, 9780306414770
DOIs
StatePublished - 1984

Publication series

NamePolymer Science and Technology
Volume25
ISSN (Print)0093-6286

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