New disordering mode for TFSI- anions: The nonequilibrium, plastic crystalline structure of Et4NTFSI

Wesley A. Henderson; Marie Herstedt; Victor G. Young; Stefano Passerini; Hugh C. De Long; Paul C. Trulove

doi:10.1021/ic0513742

New disordering mode for TFSI^- anions: The nonequilibrium, plastic crystalline structure of Et₄NTFSI

Wesley A. Henderson, Marie Herstedt, Victor G. Young, Stefano Passerini, Hugh C. De Long, Paul C. Trulove

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

84 Scopus citations

Abstract

A new TFSI^- anion disordering mode has been discovered in a supercooled plastic crystalline phase of Et₄NTFSI, which may, in part, account for the low melting points of TFSI^- salts with organic cations, thereby forming ionic liquids, and the intriguing properties of LiTFSI for lithium battery applications.

Original language	English (US)
Pages (from-to)	1412-1414
Number of pages	3
Journal	Inorganic chemistry
Volume	45
Issue number	4
DOIs	https://doi.org/10.1021/ic0513742
State	Published - Feb 20 2006

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10.1021/ic0513742

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abstract = "A new TFSI- anion disordering mode has been discovered in a supercooled plastic crystalline phase of Et4NTFSI, which may, in part, account for the low melting points of TFSI- salts with organic cations, thereby forming ionic liquids, and the intriguing properties of LiTFSI for lithium battery applications.",

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AU - Henderson, Wesley A.

AU - Herstedt, Marie

AU - Young, Victor G.

AU - Passerini, Stefano

AU - De Long, Hugh C.

AU - Trulove, Paul C.

PY - 2006/2/20

Y1 - 2006/2/20

N2 - A new TFSI- anion disordering mode has been discovered in a supercooled plastic crystalline phase of Et4NTFSI, which may, in part, account for the low melting points of TFSI- salts with organic cations, thereby forming ionic liquids, and the intriguing properties of LiTFSI for lithium battery applications.

AB - A new TFSI- anion disordering mode has been discovered in a supercooled plastic crystalline phase of Et4NTFSI, which may, in part, account for the low melting points of TFSI- salts with organic cations, thereby forming ionic liquids, and the intriguing properties of LiTFSI for lithium battery applications.

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New disordering mode for TFSI^- anions: The nonequilibrium, plastic crystalline structure of Et₄NTFSI

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