NaIO4-Mediated Selective Oxidative Halogenation of Alkenes and Aromatics Using Alkali Metal Halides

Gajanan K. Dewkar, Srinivasarao V. Narina, Arumugam Sudalai

Research output: Contribution to journalArticlepeer-review

134 Scopus citations

Abstract

(Equation presented) NaIO4 oxidizes alkali metal halides efficiently in aqueous medium to halogenate alkenes and aromatics and produce the corresponding halo derivatives in excellent regio and stereoselectivity. The system also demonstrates the asymmetric version of bromo hydroxylation using β-cyclodextrin complexes, resulting in moderate ee.

Original languageEnglish (US)
Pages (from-to)4501-4504
Number of pages4
JournalOrganic Letters
Volume5
Issue number23
DOIs
StatePublished - Nov 13 2003

Fingerprint Dive into the research topics of 'NaIO<sub>4</sub>-Mediated Selective Oxidative Halogenation of Alkenes and Aromatics Using Alkali Metal Halides'. Together they form a unique fingerprint.

Cite this