Multiple metal-metal bonds in iron-chromium complexes

P. Alex Rudd, Shengsi Liu, Nora Planas, Eckhard Bill, Laura Gagliardi, Connie C. Lu

Research output: Contribution to journalArticle

50 Scopus citations

Abstract

Mix and match: The first structural examples of M-M multiple bonds between different first-row transition metals are elucidated using X-ray crystallography (see picture; Fe pink, Cr green, P yellow, N blue), spectroscopic methods, and calculations. The Fe-Cr bonds are ultrashort (<2 Å) with highly delocalized σ and π bonds and unusually large quadrupole splittings in Mössbauer spectroscopy.

Original languageEnglish (US)
Pages (from-to)4449-4452
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number16
DOIs
StatePublished - Apr 15 2013

Keywords

  • chromium
  • heterometallic complexes
  • iron
  • metal-metal bonds
  • multiple bonds

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