Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands

David P. Klein; Victor G. Young; William B. Tolman; Lawrence Que

doi:10.1021/ic0610740

Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands

David P. Klein, Victor G. Young, William B. Tolman, Lawrence Que

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Complexes that feature a single NO bound to Fe, as postulated in various carboxylate-rich metalloproteins, were prepared by mixing Fe^II salts, NO, and the sterically encumbered 2,6-dimesitylbenzoate (Mes ₂ArCO₂^-). Among the compounds isolated are the potentially useful heterobimetallic synthon Tl(μ-Mes₂ArCO ₂)₃Fe(NO) and a novel cubane Fe₄(Mes ₂ArCO₂)₄(NO)₄(μ₃-OH) ₄ that forms in the presence of added H₂O and features syn-[FeNO]₂ units.

Original language	English (US)
Pages (from-to)	8006-8008
Number of pages	3
Journal	Inorganic chemistry
Volume	45
Issue number	20
DOIs	https://doi.org/10.1021/ic0610740
State	Published - Oct 2 2006

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title = "Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands",

abstract = "Complexes that feature a single NO bound to Fe, as postulated in various carboxylate-rich metalloproteins, were prepared by mixing FeII salts, NO, and the sterically encumbered 2,6-dimesitylbenzoate (Mes 2ArCO2-). Among the compounds isolated are the potentially useful heterobimetallic synthon Tl(μ-Mes2ArCO 2)3Fe(NO) and a novel cubane Fe4(Mes 2ArCO2)4(NO)4(μ3-OH) 4 that forms in the presence of added H2O and features syn-[FeNO]2 units.",

author = "Klein, {David P.} and Young, {Victor G.} and Tolman, {William B.} and Lawrence Que",

year = "2006",

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doi = "10.1021/ic0610740",

language = "English (US)",

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T1 - Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands

AU - Klein, David P.

AU - Young, Victor G.

AU - Tolman, William B.

AU - Que, Lawrence

PY - 2006/10/2

Y1 - 2006/10/2

N2 - Complexes that feature a single NO bound to Fe, as postulated in various carboxylate-rich metalloproteins, were prepared by mixing FeII salts, NO, and the sterically encumbered 2,6-dimesitylbenzoate (Mes 2ArCO2-). Among the compounds isolated are the potentially useful heterobimetallic synthon Tl(μ-Mes2ArCO 2)3Fe(NO) and a novel cubane Fe4(Mes 2ArCO2)4(NO)4(μ3-OH) 4 that forms in the presence of added H2O and features syn-[FeNO]2 units.

AB - Complexes that feature a single NO bound to Fe, as postulated in various carboxylate-rich metalloproteins, were prepared by mixing FeII salts, NO, and the sterically encumbered 2,6-dimesitylbenzoate (Mes 2ArCO2-). Among the compounds isolated are the potentially useful heterobimetallic synthon Tl(μ-Mes2ArCO 2)3Fe(NO) and a novel cubane Fe4(Mes 2ArCO2)4(NO)4(μ3-OH) 4 that forms in the presence of added H2O and features syn-[FeNO]2 units.

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JO - Inorganic Chemistry

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Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands

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