Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands

David P. Klein; Victor G. Young; William B. Tolman; Lawrence Que

doi:10.1021/ic0610740

Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands

David P. Klein, Victor G. Young, William B. Tolman, Lawrence Que

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Complexes that feature a single NO bound to Fe, as postulated in various carboxylate-rich metalloproteins, were prepared by mixing Fe^II salts, NO, and the sterically encumbered 2,6-dimesitylbenzoate (Mes ₂ArCO₂^-). Among the compounds isolated are the potentially useful heterobimetallic synthon Tl(μ-Mes₂ArCO ₂)₃Fe(NO) and a novel cubane Fe₄(Mes ₂ArCO₂)₄(NO)₄(μ₃-OH) ₄ that forms in the presence of added H₂O and features syn-[FeNO]₂ units.

Original language	English (US)
Pages (from-to)	8006-8008
Number of pages	3
Journal	Inorganic chemistry
Volume	45
Issue number	20
DOIs	https://doi.org/10.1021/ic0610740
State	Published - Oct 2 2006

Publisher link

10.1021/ic0610740

Find It

Find It at U of M Libraries

Cite this

@article{5b6be612a1f042b798fc82faf2d43864,

title = "Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands",

abstract = "Complexes that feature a single NO bound to Fe, as postulated in various carboxylate-rich metalloproteins, were prepared by mixing FeII salts, NO, and the sterically encumbered 2,6-dimesitylbenzoate (Mes 2ArCO2-). Among the compounds isolated are the potentially useful heterobimetallic synthon Tl(μ-Mes2ArCO 2)3Fe(NO) and a novel cubane Fe4(Mes 2ArCO2)4(NO)4(μ3-OH) 4 that forms in the presence of added H2O and features syn-[FeNO]2 units.",

author = "Klein, {David P.} and Young, {Victor G.} and Tolman, {William B.} and Lawrence Que",

year = "2006",

month = oct,

day = "2",

doi = "10.1021/ic0610740",

language = "English (US)",

volume = "45",

pages = "8006--8008",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "20",

}

TY - JOUR

T1 - Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands

AU - Klein, David P.

AU - Young, Victor G.

AU - Tolman, William B.

AU - Que, Lawrence

PY - 2006/10/2

Y1 - 2006/10/2

N2 - Complexes that feature a single NO bound to Fe, as postulated in various carboxylate-rich metalloproteins, were prepared by mixing FeII salts, NO, and the sterically encumbered 2,6-dimesitylbenzoate (Mes 2ArCO2-). Among the compounds isolated are the potentially useful heterobimetallic synthon Tl(μ-Mes2ArCO 2)3Fe(NO) and a novel cubane Fe4(Mes 2ArCO2)4(NO)4(μ3-OH) 4 that forms in the presence of added H2O and features syn-[FeNO]2 units.

AB - Complexes that feature a single NO bound to Fe, as postulated in various carboxylate-rich metalloproteins, were prepared by mixing FeII salts, NO, and the sterically encumbered 2,6-dimesitylbenzoate (Mes 2ArCO2-). Among the compounds isolated are the potentially useful heterobimetallic synthon Tl(μ-Mes2ArCO 2)3Fe(NO) and a novel cubane Fe4(Mes 2ArCO2)4(NO)4(μ3-OH) 4 that forms in the presence of added H2O and features syn-[FeNO]2 units.

UR - http://www.scopus.com/inward/record.url?scp=33750290420&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33750290420&partnerID=8YFLogxK

U2 - 10.1021/ic0610740

DO - 10.1021/ic0610740

M3 - Article

C2 - 16999396

AN - SCOPUS:33750290420

SN - 0020-1669

VL - 45

SP - 8006

EP - 8008

JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 20

ER -

Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands

Abstract

Publisher link

Find It

Other files and links

Fingerprint

Cite this