Mono endo-6- And bis endo,endo-12-N,N-diethylcarbamoyl derivatives of Tröger’s Base. Synthesis and exo-endo isomerization study

Keyphrases

• Isomerization 100%
• CD3OD 100%
• Reaction Time 66%
• Deuterium 66%
• Carbamoyl 66%
• Single Crystal X-ray 33%
• 1H nuclear Magnetic Resonance (1H NMR) 33%
• Synthetic Routes 33%
• X-ray Crystallographic Analysis 33%
• Stereochemical Assignment 33%
• Structural Assignment 33%
• Enolates 33%
• Iminium Ion 33%
• Quench Test 33%
• Proton Source 33%
• Deuterium Incorporation 33%
• Ring-opening Mechanism 33%

Chemistry

• Isomerization 100%
• Base 100%
• Deuterium 100%
• Carbamoyl 66%
• 1H NMR Spectroscopy 33%
• Single Crystalline Solid 33%
• Ring Opening Reaction 33%
• Local-Density Approximation 33%
• Enolates 33%
• Iminium Ion 33%
• X-Ray Crystallographic Analysis 33%

Biochemistry, Genetics and Molecular Biology

• Isomerization 100%
• X Ray 50%
• Ring Opening 50%