Mono- and digallane complexes of a tridentate amido-diamine ligand

Bing Luo, Benjamin E. Kucera, Wayne L. Gladfelter

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

Bis(2-dimethylaminoethyl)amido gallane, H2GaN(CH 2CH2-NMe2)2, that melts at 27 °C and remains stable upon heating at 55 °C for two days, was synthesized either from the reaction of the quinuclidine adduct of monochlorogallane with the lithium salt of the corresponding amine, or from the reaction of trimethylamine gallane and the amine; the latter affords an unusual co-product with both GaH2 and GaH3 bonded to the same amido nitrogen.

Original languageEnglish (US)
Pages (from-to)3463-3465
Number of pages3
JournalChemical Communications
Issue number27
DOIs
StatePublished - Jul 21 2005

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