TY - JOUR
T1 - Mono-and bis-tolylterpyridine iridium(III) complexes
AU - Hinkle, Lindsay M.
AU - Young, Victor G.
AU - Mann, Kent R.
PY - 2010
Y1 - 2010
N2 - The first structure report of trichlorido[4′-(p-tolyl)-2,2′: 6′,2′′-terpyridine]iridium(III) dimethyl sulfoxide solvate, [IrCl3(C22H17N3)]·C 2H6OS, (I), is presented, along with a higher-symmetry setting of previously reported bis-[4′-(p-tolyl)-2,2′:6′, 2′′-terpyridine]iridium(III) tris-(hexafluoridophosphate) acetonitrile disolvate, [Ir(C22H17N3) 2](PF6)3·2C2H3N, (II) [Yoshikawa, Yamabe, Kanehisa, Kai, Takashima & Tsukahara (2007). Eur. J. Inorg. Chem. pp. 1911-1919]. For (I), the data were collected with synchrotron radiation and the dimethyl sulfoxide solvent mol-ecule is disordered over three positions, one of which is an inversion center. The previously reported structure of (II) is presented in the more appropriate C2/c space group. The iridium complex and one PF6- anion lie on twofold axes in this structure, making half of the mol-ecule unique.
AB - The first structure report of trichlorido[4′-(p-tolyl)-2,2′: 6′,2′′-terpyridine]iridium(III) dimethyl sulfoxide solvate, [IrCl3(C22H17N3)]·C 2H6OS, (I), is presented, along with a higher-symmetry setting of previously reported bis-[4′-(p-tolyl)-2,2′:6′, 2′′-terpyridine]iridium(III) tris-(hexafluoridophosphate) acetonitrile disolvate, [Ir(C22H17N3) 2](PF6)3·2C2H3N, (II) [Yoshikawa, Yamabe, Kanehisa, Kai, Takashima & Tsukahara (2007). Eur. J. Inorg. Chem. pp. 1911-1919]. For (I), the data were collected with synchrotron radiation and the dimethyl sulfoxide solvent mol-ecule is disordered over three positions, one of which is an inversion center. The previously reported structure of (II) is presented in the more appropriate C2/c space group. The iridium complex and one PF6- anion lie on twofold axes in this structure, making half of the mol-ecule unique.
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U2 - 10.1107/S0108270110002751
DO - 10.1107/S0108270110002751
M3 - Article
C2 - 20203396
AN - SCOPUS:77949279245
SN - 0108-2701
VL - 66
SP - m62-m64
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 3
ER -