Modified-Graphene-Oxide-Containing Styrene Masterbatches for Thermosets

Siyao He, Yuqiang Qian, Kunwei Liu, Christopher W. Macosko, Andreas Stein

Research output: Contribution to journalArticlepeer-review

8 Scopus citations


Incorporating graphene-based nanomaterials into thermosetting resins is challenging at an industrial-scale. To address this issue, we prepared a styrene masterbatch containing chemically modified graphene oxide (mGO) and added it to unsaturated polyester and vinyl ester resins via simple mechanical mixing to generate homogeneous mGO/resin dispersions. For comparison, oven-dried or freeze-dried mGO was also blended into resin using the same mechanical mixing conditions. At low mGO loading levels of 0.02-0.08 wt %, composites made with oven-dried or freeze-dried mGO show the highest increase in fracture toughness but also the most severe decrease in flexural strength, whereas composites prepared from the mGO masterbatch show the best dispersion homogeneity and better retention of flexural strength while exhibiting only slightly less increase in toughness. The masterbatch process offers an economical way of producing high-quality mGO/resin dispersions.

Original languageEnglish (US)
Pages (from-to)11443-11450
Number of pages8
JournalIndustrial and Engineering Chemistry Research
Issue number40
StatePublished - Oct 11 2017

Bibliographical note

Funding Information:
This research was funded by Adama Materials. Resin composite samples were prepared by Mr. John Ryder. The authors thank Robert Ferris and Frank Thibodeau for helpful discussions and Professor R. Lee Penn and Professor Xiang Chen for providing access to XRD and VLM equipment, respectively. Parts of this work were carried out in the Characterization Facility, University of Minnesota, a member of the NSF-funded Materials Research Facilities Network ( via the MRSEC program.

Publisher Copyright:
© 2017 American Chemical Society.


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