Mixed metal bis(μ-oxo) complexes with [CuM(μ-O)2]n+(M = Ni(III) or Pd(II)) cores

Nermeen W. Aboelella; John T. York; Anne M. Reynolds; Christopher R. Kinsinger; Christopher J. Cramer; Charles G. Riordan; William B. Tolman

doi:10.1039/b404640d

Mixed metal bis(μ-oxo) complexes with [CuM(μ-O)₂]ⁿ⁺(M = Ni(III) or Pd(II)) cores

Nermeen W. Aboelella, John T. York, Anne M. Reynolds, Christopher R. Kinsinger, Christopher J. Cramer, Charles G. Riordan, William B. Tolman

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Abstract

Two highly reactive heterodinuclear bis(μ-oxo) complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at −80 °C and were identified by UV-vis, EPR/NMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional calculations.

Original language	English (US)
Pages (from-to)	1716-1717
Number of pages	2
Journal	Chemical Communications
Volume	4
Issue number	15
DOIs	https://doi.org/10.1039/b404640d
State	Published - 2004

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10.1039/b404640d

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title = "Mixed metal bis(μ-oxo) complexes with [CuM(μ-O)2]n+(M = Ni(III) or Pd(II)) cores",

abstract = "Two highly reactive heterodinuclear bis(μ-oxo) complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at −80 °C and were identified by UV-vis, EPR/NMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional calculations.",

author = "Aboelella, {Nermeen W.} and York, {John T.} and Reynolds, {Anne M.} and Kinsinger, {Christopher R.} and Cramer, {Christopher J.} and Riordan, {Charles G.} and Tolman, {William B.}",

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T1 - Mixed metal bis(μ-oxo) complexes with [CuM(μ-O)2]n+(M = Ni(III) or Pd(II)) cores

AU - Aboelella, Nermeen W.

AU - York, John T.

AU - Reynolds, Anne M.

AU - Kinsinger, Christopher R.

AU - Cramer, Christopher J.

AU - Riordan, Charles G.

AU - Tolman, William B.

PY - 2004

Y1 - 2004

N2 - Two highly reactive heterodinuclear bis(μ-oxo) complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at −80 °C and were identified by UV-vis, EPR/NMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional calculations.

AB - Two highly reactive heterodinuclear bis(μ-oxo) complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at −80 °C and were identified by UV-vis, EPR/NMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional calculations.

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DO - 10.1039/b404640d

M3 - Article

C2 - 15278152

AN - SCOPUS:4344639645

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JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

Mixed metal bis(μ-oxo) complexes with [CuM(μ-O)₂]ⁿ⁺(M = Ni(III) or Pd(II)) cores

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