Mild and efficient synthesis of iodylarenes using Oxone as oxidant

Natalia Soldatova; Pavel Postnikov; Anna A. Troyan; Akira Yoshimura; Mekhman S. Yusubov; Viktor Zhdankin

doi:10.1016/j.tetlet.2016.08.038

Mild and efficient synthesis of iodylarenes using Oxone as oxidant

Natalia Soldatova, Pavel Postnikov, Anna A. Troyan, Akira Yoshimura, Mekhman S. Yusubov, Viktor Zhdankin

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

Original language	English (US)
Pages (from-to)	4254-4256
Number of pages	3
Journal	Tetrahedron Letters
Volume	57
Issue number	37
DOIs	https://doi.org/10.1016/j.tetlet.2016.08.038
State	Published - 2016

Bibliographical note

Funding Information:
This work was supported by research grants from the National Science Foundation ( CHE-1262479 and MRI-1420373 ) and by the Russian Science Foundation ( RSF-16-13-10081 ).

Publisher Copyright:
© 2016 Elsevier Ltd

Keywords

Hypervalent iodine
Iodine
Iodylarenes
Oxidation
Oxone

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10.1016/j.tetlet.2016.08.038

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title = "Mild and efficient synthesis of iodylarenes using Oxone as oxidant",

abstract = "Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.",

keywords = "Hypervalent iodine, Iodine, Iodylarenes, Oxidation, Oxone",

author = "Natalia Soldatova and Pavel Postnikov and Troyan, {Anna A.} and Akira Yoshimura and Yusubov, {Mekhman S.} and Viktor Zhdankin",

note = "Funding Information: This work was supported by research grants from the National Science Foundation ( CHE-1262479 and MRI-1420373 ) and by the Russian Science Foundation ( RSF-16-13-10081 ). Publisher Copyright: {\textcopyright} 2016 Elsevier Ltd",

year = "2016",

doi = "10.1016/j.tetlet.2016.08.038",

language = "English (US)",

volume = "57",

pages = "4254--4256",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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T1 - Mild and efficient synthesis of iodylarenes using Oxone as oxidant

AU - Soldatova, Natalia

AU - Postnikov, Pavel

AU - Troyan, Anna A.

AU - Yoshimura, Akira

AU - Yusubov, Mekhman S.

AU - Zhdankin, Viktor

N1 - Funding Information: This work was supported by research grants from the National Science Foundation ( CHE-1262479 and MRI-1420373 ) and by the Russian Science Foundation ( RSF-16-13-10081 ). Publisher Copyright: © 2016 Elsevier Ltd

PY - 2016

Y1 - 2016

N2 - Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

AB - Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

KW - Hypervalent iodine

KW - Iodine

KW - Iodylarenes

KW - Oxidation

KW - Oxone

UR - http://www.scopus.com/inward/record.url?scp=84983071330&partnerID=8YFLogxK

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U2 - 10.1016/j.tetlet.2016.08.038

DO - 10.1016/j.tetlet.2016.08.038

M3 - Article

AN - SCOPUS:84983071330

SN - 0040-4039

VL - 57

SP - 4254

EP - 4256

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 37

ER -

Mild and efficient synthesis of iodylarenes using Oxone as oxidant

Abstract

Bibliographical note

Keywords

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