Microwave-induced clay-catalyzed ring opening of N-tosylaziridines: A green approach to achiral and chiral diamines

Upender K. Nadir; Anamika Singh

doi:10.1016/j.tetlet.2005.01.132

Microwave-induced clay-catalyzed ring opening of N-tosylaziridines: A green approach to achiral and chiral diamines

Upender K. Nadir
, Anamika Singh

Medicinal Chemistry

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

N-Tosylaziridines react efficiently with amines in the presence of Montmorillonite K-10 as catalyst under microwave irradiation in solvent-free conditions to yield the corresponding achiral and chiral diamines regio- and stereoselectively, in a few minutes and in high yields.

Original language	English (US)
Pages (from-to)	2083-2086
Number of pages	4
Journal	Tetrahedron Letters
Volume	46
Issue number	12
DOIs	https://doi.org/10.1016/j.tetlet.2005.01.132
State	Published - Mar 21 2005

Bibliographical note

Funding Information:
We thank the Council of Scientific and Industrial research (CSIR), New Delhi for financial support of this work and for a fellowship to A.S.

Keywords

Aziridines
Clay
Diamines
Microwave

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10.1016/j.tetlet.2005.01.132

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title = "Microwave-induced clay-catalyzed ring opening of N-tosylaziridines: A green approach to achiral and chiral diamines",

abstract = "N-Tosylaziridines react efficiently with amines in the presence of Montmorillonite K-10 as catalyst under microwave irradiation in solvent-free conditions to yield the corresponding achiral and chiral diamines regio- and stereoselectively, in a few minutes and in high yields.",

keywords = "Aziridines, Clay, Diamines, Microwave",

author = "Nadir, \{Upender K.\} and Anamika Singh",

note = "Funding Information: We thank the Council of Scientific and Industrial research (CSIR), New Delhi for financial support of this work and for a fellowship to A.S.",

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journal = "Tetrahedron Letters",

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T1 - Microwave-induced clay-catalyzed ring opening of N-tosylaziridines

T2 - A green approach to achiral and chiral diamines

AU - Nadir, Upender K.

AU - Singh, Anamika

N1 - Funding Information: We thank the Council of Scientific and Industrial research (CSIR), New Delhi for financial support of this work and for a fellowship to A.S.

PY - 2005/3/21

Y1 - 2005/3/21

N2 - N-Tosylaziridines react efficiently with amines in the presence of Montmorillonite K-10 as catalyst under microwave irradiation in solvent-free conditions to yield the corresponding achiral and chiral diamines regio- and stereoselectively, in a few minutes and in high yields.

AB - N-Tosylaziridines react efficiently with amines in the presence of Montmorillonite K-10 as catalyst under microwave irradiation in solvent-free conditions to yield the corresponding achiral and chiral diamines regio- and stereoselectively, in a few minutes and in high yields.

KW - Aziridines

KW - Clay

KW - Diamines

KW - Microwave

UR - https://www.scopus.com/pages/publications/14644415518

UR - https://www.scopus.com/pages/publications/14644415518#tab=citedBy

U2 - 10.1016/j.tetlet.2005.01.132

DO - 10.1016/j.tetlet.2005.01.132

M3 - Article

AN - SCOPUS:14644415518

SN - 0040-4039

VL - 46

SP - 2083

EP - 2086

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 12

ER -

Microwave-induced clay-catalyzed ring opening of N-tosylaziridines: A green approach to achiral and chiral diamines

Abstract

Bibliographical note

Keywords

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