Microwave-induced clay-catalyzed ring opening of N-tosylaziridines: A green approach to achiral and chiral diamines

Upender K. Nadir; Anamika Singh

doi:10.1016/j.tetlet.2005.01.132

Microwave-induced clay-catalyzed ring opening of N-tosylaziridines: A green approach to achiral and chiral diamines

Upender K. Nadir, Anamika Singh

Medicinal Chemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

N-Tosylaziridines react efficiently with amines in the presence of Montmorillonite K-10 as catalyst under microwave irradiation in solvent-free conditions to yield the corresponding achiral and chiral diamines regio- and stereoselectively, in a few minutes and in high yields.

Original language	English (US)
Pages (from-to)	2083-2086
Number of pages	4
Journal	Tetrahedron Letters
Volume	46
Issue number	12
DOIs	https://doi.org/10.1016/j.tetlet.2005.01.132
State	Published - Mar 21 2005

Bibliographical note

Funding Information:
We thank the Council of Scientific and Industrial research (CSIR), New Delhi for financial support of this work and for a fellowship to A.S.

Copyright:
Copyright 2017 Elsevier B.V., All rights reserved.

Keywords

Aziridines
Clay
Diamines
Microwave

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abstract = "N-Tosylaziridines react efficiently with amines in the presence of Montmorillonite K-10 as catalyst under microwave irradiation in solvent-free conditions to yield the corresponding achiral and chiral diamines regio- and stereoselectively, in a few minutes and in high yields.",

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author = "Nadir, {Upender K.} and Anamika Singh",

note = "Funding Information: We thank the Council of Scientific and Industrial research (CSIR), New Delhi for financial support of this work and for a fellowship to A.S. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.",

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doi = "10.1016/j.tetlet.2005.01.132",

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T2 - A green approach to achiral and chiral diamines

AU - Nadir, Upender K.

AU - Singh, Anamika

N1 - Funding Information: We thank the Council of Scientific and Industrial research (CSIR), New Delhi for financial support of this work and for a fellowship to A.S. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.

PY - 2005/3/21

Y1 - 2005/3/21

N2 - N-Tosylaziridines react efficiently with amines in the presence of Montmorillonite K-10 as catalyst under microwave irradiation in solvent-free conditions to yield the corresponding achiral and chiral diamines regio- and stereoselectively, in a few minutes and in high yields.

AB - N-Tosylaziridines react efficiently with amines in the presence of Montmorillonite K-10 as catalyst under microwave irradiation in solvent-free conditions to yield the corresponding achiral and chiral diamines regio- and stereoselectively, in a few minutes and in high yields.

KW - Aziridines

KW - Clay

KW - Diamines

KW - Microwave

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JF - Tetrahedron Letters

SN - 0040-4039

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ER -

Microwave-induced clay-catalyzed ring opening of N-tosylaziridines: A green approach to achiral and chiral diamines

Abstract

Bibliographical note

Keywords

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