MFI zeolite membranes from a- and randomly oriented monolayers

Jungkyu Choi; Shubhajit Ghosh; Lisa King; Michael Tsapatsis

doi:10.1007/s10450-006-0564-y

MFI zeolite membranes from a- and randomly oriented monolayers

Jungkyu Choi
, Shubhajit Ghosh
, Lisa King
, Michael Tsapatsis

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

c-Oriented columnar MFI films made by secondary growth of randomly oriented seed monolayers, deposited using sonication-assisted covalent attachment, exhibit n-hexane/2,2-dimethylbutane separation factor of up to 10 ⁴, n-/i-butane separation factor of up to 50, and p-/o-xylene separation factor of up to 2. A MFI film from a-oriented seed layer shows lower separation factors for the linear vs. branched isomers but higher separation factor for p-/o-xylene.

Original language	English (US)
Pages (from-to)	339-360
Number of pages	22
Journal	Adsorption
Volume	12
Issue number	5-6
DOIs	https://doi.org/10.1007/s10450-006-0564-y
State	Published - Sep 2006

Bibliographical note

Funding Information:
Acknowledgments Funding from NSF (CTS-0522518) and UOP LLC through IPrime is gratefully acknowledged. All char- acterizations were performed at the University of Minnesota Characterization Facility supported from NSF through the National Nanotechnology Infrastructure Network (NNIN).

Keywords

Butane
Hexane
MFI
Permeation
Preferred orientation
Separation
Xylene
Zeolite

Publisher link

10.1007/s10450-006-0564-y

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title = "MFI zeolite membranes from a- and randomly oriented monolayers",

abstract = "c-Oriented columnar MFI films made by secondary growth of randomly oriented seed monolayers, deposited using sonication-assisted covalent attachment, exhibit n-hexane/2,2-dimethylbutane separation factor of up to 10 4, n-/i-butane separation factor of up to 50, and p-/o-xylene separation factor of up to 2. A MFI film from a-oriented seed layer shows lower separation factors for the linear vs. branched isomers but higher separation factor for p-/o-xylene.",

keywords = "Butane, Hexane, MFI, Permeation, Preferred orientation, Separation, Xylene, Zeolite",

author = "Jungkyu Choi and Shubhajit Ghosh and Lisa King and Michael Tsapatsis",

note = "Funding Information: Acknowledgments Funding from NSF (CTS-0522518) and UOP LLC through IPrime is gratefully acknowledged. All char- acterizations were performed at the University of Minnesota Characterization Facility supported from NSF through the National Nanotechnology Infrastructure Network (NNIN).",

year = "2006",

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doi = "10.1007/s10450-006-0564-y",

language = "English (US)",

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T1 - MFI zeolite membranes from a- and randomly oriented monolayers

AU - Choi, Jungkyu

AU - Ghosh, Shubhajit

AU - King, Lisa

AU - Tsapatsis, Michael

N1 - Funding Information: Acknowledgments Funding from NSF (CTS-0522518) and UOP LLC through IPrime is gratefully acknowledged. All char- acterizations were performed at the University of Minnesota Characterization Facility supported from NSF through the National Nanotechnology Infrastructure Network (NNIN).

PY - 2006/9

Y1 - 2006/9

N2 - c-Oriented columnar MFI films made by secondary growth of randomly oriented seed monolayers, deposited using sonication-assisted covalent attachment, exhibit n-hexane/2,2-dimethylbutane separation factor of up to 10 4, n-/i-butane separation factor of up to 50, and p-/o-xylene separation factor of up to 2. A MFI film from a-oriented seed layer shows lower separation factors for the linear vs. branched isomers but higher separation factor for p-/o-xylene.

AB - c-Oriented columnar MFI films made by secondary growth of randomly oriented seed monolayers, deposited using sonication-assisted covalent attachment, exhibit n-hexane/2,2-dimethylbutane separation factor of up to 10 4, n-/i-butane separation factor of up to 50, and p-/o-xylene separation factor of up to 2. A MFI film from a-oriented seed layer shows lower separation factors for the linear vs. branched isomers but higher separation factor for p-/o-xylene.

KW - Butane

KW - Hexane

KW - MFI

KW - Permeation

KW - Preferred orientation

KW - Separation

KW - Xylene

KW - Zeolite

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DO - 10.1007/s10450-006-0564-y

M3 - Article

AN - SCOPUS:33845457678

SN - 0929-5607

VL - 12

SP - 339

EP - 360

JO - Adsorption

JF - Adsorption

IS - 5-6

ER -

MFI zeolite membranes from a- and randomly oriented monolayers

Abstract

Bibliographical note

Keywords

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