Metal-alane adducts with zero-valent nickel, cobalt, and iron

P. Alex Rudd; Shengsi Liu; Laura Gagliardi; Victor G. Young; Connie C. Lu

doi:10.1021/ja2099744

Metal-alane adducts with zero-valent nickel, cobalt, and iron

P. Alex Rudd, Shengsi Liu, Laura Gagliardi, Victor G. Young, Connie C. Lu

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

164 Scopus citations

Abstract

Coordination complexes that pair a zero-valent transition metal (Ni, Co, Fe) and an aluminum(III) center have been prepared. They add to the few examples of structurally characterized metal alanes and are the first reported metallalumatranes. To understand the M-Al interaction and gauge the effect of varying the late metal, the complexes were characterized by X-ray crystallography, electrochemistry, UV-Vis-NIR and NMR spectroscopies, and theoretical calculations. The M-Al bond strength decreases with varying M in the order Ni > Co > Fe.

Original language	English (US)
Pages (from-to)	20724-20727
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	51
DOIs	https://doi.org/10.1021/ja2099744
State	Published - Dec 28 2011

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abstract = "Coordination complexes that pair a zero-valent transition metal (Ni, Co, Fe) and an aluminum(III) center have been prepared. They add to the few examples of structurally characterized metal alanes and are the first reported metallalumatranes. To understand the M-Al interaction and gauge the effect of varying the late metal, the complexes were characterized by X-ray crystallography, electrochemistry, UV-Vis-NIR and NMR spectroscopies, and theoretical calculations. The M-Al bond strength decreases with varying M in the order Ni > Co > Fe.",

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year = "2011",

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AU - Rudd, P. Alex

AU - Liu, Shengsi

AU - Gagliardi, Laura

AU - Young, Victor G.

AU - Lu, Connie C.

PY - 2011/12/28

Y1 - 2011/12/28

N2 - Coordination complexes that pair a zero-valent transition metal (Ni, Co, Fe) and an aluminum(III) center have been prepared. They add to the few examples of structurally characterized metal alanes and are the first reported metallalumatranes. To understand the M-Al interaction and gauge the effect of varying the late metal, the complexes were characterized by X-ray crystallography, electrochemistry, UV-Vis-NIR and NMR spectroscopies, and theoretical calculations. The M-Al bond strength decreases with varying M in the order Ni > Co > Fe.

AB - Coordination complexes that pair a zero-valent transition metal (Ni, Co, Fe) and an aluminum(III) center have been prepared. They add to the few examples of structurally characterized metal alanes and are the first reported metallalumatranes. To understand the M-Al interaction and gauge the effect of varying the late metal, the complexes were characterized by X-ray crystallography, electrochemistry, UV-Vis-NIR and NMR spectroscopies, and theoretical calculations. The M-Al bond strength decreases with varying M in the order Ni > Co > Fe.

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Metal-alane adducts with zero-valent nickel, cobalt, and iron

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