Melting of microgel colloidal crystals

Yi Peng, Ziren Wang, Yilong Han

Research output: Contribution to journalConference articlepeer-review

4 Scopus citations

Abstract

We experimentally studied the melting of colloidal crystals composed of diameter-tunable microgel spheres by bright-field and confocal video microscopies at the single-particle level. Thick (> 4 layers) and thin (≤ 4 layers) films exhibited dramatically different melting kinetics. Thick films melted heterogeneously from grain boundaries in polycrystals and from surfaces in single crystals, while thin films melted homogeneously even in polycrystals. A novel heterogeneous melting at dislocation was observed in 5- to 12-layer films. The equilibrium phase behaviors in three thickness regimes were all different: thick films had a crystal-liquid coexistence regime which decreased with the film thickness and vanished at 4 layers, thin crystalline films melted into liquids in one step, while monolayers melted in two steps with an intermediate hexatic phase.

Original languageEnglish (US)
Article number012010
JournalJournal of Physics: Conference Series
Volume319
Issue number1
DOIs
StatePublished - 2011
Event12th International Symposium on Continuum Models and Discrete Systems, CMDS-12 - Kolkata, India
Duration: Feb 21 2011Feb 25 2011

Fingerprint Dive into the research topics of 'Melting of microgel colloidal crystals'. Together they form a unique fingerprint.

Cite this