Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin]+[Co(CO)4]- catalyst

Jessica R. Lamb; Yukyung Jung; Geoffrey W. Coates

doi:10.1039/c4qo00324a

Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin]⁺[Co(CO)₄]^- catalyst

Jessica R. Lamb, Yukyung Jung, Geoffrey W. Coates

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47 Scopus citations

Abstract

A Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using a well-defined aluminum porphyrin catalyst is reported. This reaction shows good functional group tolerance under mild reaction conditions to selectively give methyl ketones in excellent yields.

Original language	English (US)
Pages (from-to)	346-349
Number of pages	4
Journal	Organic Chemistry Frontiers
Volume	2
Issue number	4
DOIs	https://doi.org/10.1039/c4qo00324a
State	Published - Apr 2015
Externally published	Yes

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title = "Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin]+[Co(CO)4]- catalyst",

abstract = "A Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using a well-defined aluminum porphyrin catalyst is reported. This reaction shows good functional group tolerance under mild reaction conditions to selectively give methyl ketones in excellent yields.",

author = "Lamb, {Jessica R.} and Yukyung Jung and Coates, {Geoffrey W.}",

year = "2015",

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doi = "10.1039/c4qo00324a",

language = "English (US)",

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journal = "Organic Chemistry Frontiers",

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publisher = "Royal Society of Chemistry",

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AU - Jung, Yukyung

AU - Coates, Geoffrey W.

PY - 2015/4

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IS - 4

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Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin]⁺[Co(CO)₄]^- catalyst

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