Mechanistic Duality in Tertiary Amine Additions to Thermally Generated Hexadehydro-Diels-Alder Benzynes

Keyphrases

• Hexadehydro-Diels-Alder 100%
• Benzyne 100%
• Tertiary Amine 100%
• Amine Addition 100%
• Amines 33%
• Alkenes 33%
• Proton 33%
• Aryl 33%
• Nucleophile 33%
• Protonation 33%
• N Atoms 33%
• Ammonium 33%
• Protic 33%
• Internal Hydrogen 33%
• Aniline 33%
• Zwitterionic Intermediate 33%
• Amino Alcohols 33%
• Trialkylamine 33%
• Hydrogen Bond (H-bond) 33%
• O-atom 33%

Chemistry

• Diels-Alder Reaction 100%
• Benzyne 100%
• Tertiary Amine 100%
• Alkene 33%
• Hydrogen Bonding 33%
• Ammonium 33%
• Amine 33%
• Nucleophile 33%
• Amino Alcohol 33%
• protonation 33%
• Aniline 33%