Measurement of dipolar couplings in partially oriented molecules by local field NMR spectroscopy with low-power decoupling

Malgorzata Marjanska; Franca Castiglione; Jamie D. Walls; Alexander Pines

doi:10.1016/S1090-7807(02)00059-9

Measurement of dipolar couplings in partially oriented molecules by local field NMR spectroscopy with low-power decoupling

Malgorzata Marjanska
, Franca Castiglione
, Jamie D. Walls
, Alexander Pines

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Low-power phase-modulated Lee-Goldburg homonuclear decoupling was used to record PDLF spectra of fluorine-substituted benzene derivatives dissolved in nematic thermotropic liquid crystalline solvents. The low-power decoupling minimizes sample heating during RF irradiation while still achieving highly resolved PDLF spectra. The method is illustrated by recording spectra for 1,3-dichloro-4-fluoro-5-nitrobenzene, 1,3-dichloro-4-fluorobenzene, and 1,2-difluorobenzene dissolved in different nematic solvents.

Original language	English (US)
Pages (from-to)	52-59
Number of pages	8
Journal	Journal of Magnetic Resonance
Volume	158
Issue number	1-2
DOIs	https://doi.org/10.1016/S1090-7807(02)00059-9
State	Published - 2002
Externally published	Yes

Bibliographical note

Funding Information:
The authors thank Dr. J. Granwehr for comments about the paper. This work was supported by the Director, Office of Science, Office of Basic Energy Sciences, Materials Sciences Division, of the US Department of Energy under Contract DE-AC03-76SF00098.

Keywords

Heteronuclear spin-spin couplings
Liquid crystalline solvents
Multiple pulse sequence
NMR
PDLF
PMLG
Phase-modulated Lee-Goldburg
Proton-detected local field

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10.1016/S1090-7807(02)00059-9

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@article{9ddf7935df8a441aa63c6d0d396bfee3,

title = "Measurement of dipolar couplings in partially oriented molecules by local field NMR spectroscopy with low-power decoupling",

abstract = "Low-power phase-modulated Lee-Goldburg homonuclear decoupling was used to record PDLF spectra of fluorine-substituted benzene derivatives dissolved in nematic thermotropic liquid crystalline solvents. The low-power decoupling minimizes sample heating during RF irradiation while still achieving highly resolved PDLF spectra. The method is illustrated by recording spectra for 1,3-dichloro-4-fluoro-5-nitrobenzene, 1,3-dichloro-4-fluorobenzene, and 1,2-difluorobenzene dissolved in different nematic solvents.",

keywords = "Heteronuclear spin-spin couplings, Liquid crystalline solvents, Multiple pulse sequence, NMR, PDLF, PMLG, Phase-modulated Lee-Goldburg, Proton-detected local field",

author = "Malgorzata Marjanska and Franca Castiglione and Walls, \{Jamie D.\} and Alexander Pines",

note = "Funding Information: The authors thank Dr. J. Granwehr for comments about the paper. This work was supported by the Director, Office of Science, Office of Basic Energy Sciences, Materials Sciences Division, of the US Department of Energy under Contract DE-AC03-76SF00098.",

year = "2002",

doi = "10.1016/S1090-7807(02)00059-9",

language = "English (US)",

volume = "158",

pages = "52--59",

journal = "Journal of Magnetic Resonance",

issn = "1090-7807",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - Measurement of dipolar couplings in partially oriented molecules by local field NMR spectroscopy with low-power decoupling

AU - Marjanska, Malgorzata

AU - Castiglione, Franca

AU - Walls, Jamie D.

AU - Pines, Alexander

N1 - Funding Information: The authors thank Dr. J. Granwehr for comments about the paper. This work was supported by the Director, Office of Science, Office of Basic Energy Sciences, Materials Sciences Division, of the US Department of Energy under Contract DE-AC03-76SF00098.

PY - 2002

Y1 - 2002

N2 - Low-power phase-modulated Lee-Goldburg homonuclear decoupling was used to record PDLF spectra of fluorine-substituted benzene derivatives dissolved in nematic thermotropic liquid crystalline solvents. The low-power decoupling minimizes sample heating during RF irradiation while still achieving highly resolved PDLF spectra. The method is illustrated by recording spectra for 1,3-dichloro-4-fluoro-5-nitrobenzene, 1,3-dichloro-4-fluorobenzene, and 1,2-difluorobenzene dissolved in different nematic solvents.

AB - Low-power phase-modulated Lee-Goldburg homonuclear decoupling was used to record PDLF spectra of fluorine-substituted benzene derivatives dissolved in nematic thermotropic liquid crystalline solvents. The low-power decoupling minimizes sample heating during RF irradiation while still achieving highly resolved PDLF spectra. The method is illustrated by recording spectra for 1,3-dichloro-4-fluoro-5-nitrobenzene, 1,3-dichloro-4-fluorobenzene, and 1,2-difluorobenzene dissolved in different nematic solvents.

KW - Heteronuclear spin-spin couplings

KW - Liquid crystalline solvents

KW - Multiple pulse sequence

KW - NMR

KW - PDLF

KW - PMLG

KW - Phase-modulated Lee-Goldburg

KW - Proton-detected local field

UR - https://www.scopus.com/pages/publications/57249091858

UR - https://www.scopus.com/pages/publications/57249091858#tab=citedBy

U2 - 10.1016/S1090-7807(02)00059-9

DO - 10.1016/S1090-7807(02)00059-9

M3 - Article

AN - SCOPUS:57249091858

SN - 1090-7807

VL - 158

SP - 52

EP - 59

JO - Journal of Magnetic Resonance

JF - Journal of Magnetic Resonance

IS - 1-2

ER -

Measurement of dipolar couplings in partially oriented molecules by local field NMR spectroscopy with low-power decoupling

Abstract

Bibliographical note

Keywords

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