Mass transfer in pH-sensitive hydrogels

Stevin H. Gehrke, E. L. Cussler

Research output: Contribution to journalArticlepeer-review

119 Scopus citations

Abstract

This paper describes measurements of solute and solvent transport in swollen, swelling, and collapsing hydrogels. Solute diffusion in swollen gels follows Fick's law, with diffusion coefficients varying only slightly with the degree of swelling. Solvent diffusion into swelling gels is affected both by Fick's law and by the rates of ion exchange. Solvent diffusion in collapsing gels is faster than that in swelling gels, and is effectively described by Fick's law.

Original languageEnglish (US)
Pages (from-to)559-566
Number of pages8
JournalChemical Engineering Science
Volume44
Issue number3
DOIs
StatePublished - 1989

Bibliographical note

Funding Information:
Acknowledgemenrs-This paper is a contribution from the Center for Interfacial Engineering at the University of Minnesota. It was supported by the National Science Foundation grant CPE 8408999 and by Hoechst-Celanese.

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