Manganese fischer carbene chemistry: Reactions of cpʹ(co)2mn=c(ome/oli)r with enynes, 1-hexyne, and acrylates

Thomas R. Hoye, Gretchen M. Rehberg

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

Reactions of the title carbene complexes, both the neutral methoxy (1a,b) and anionic “lithoxy” (1c) versions, with α,ω-enynes 2 give the bicyclic cyclopropanes 3. The anion also reacts with 1-hexyne to give the butenolide 5 and with acrylate esters to give the γ-keto esters 8.

Original languageEnglish (US)
Pages (from-to)3014-3015
Number of pages2
JournalOrganometallics
Volume9
Issue number12
DOIs
StatePublished - Jan 1 1990

Fingerprint

Dive into the research topics of 'Manganese fischer carbene chemistry: Reactions of cpʹ(co)<sub>2</sub>mn=c(ome/oli)r with enynes, 1-hexyne, and acrylates'. Together they form a unique fingerprint.

Cite this