Lowering the percolation threshold of conductive composites using particulate polymer microstructure

Jaime C. Grunlan, William W. Gerberich, Lorraine F. Francis

Research output: Contribution to journalArticlepeer-review

105 Scopus citations

Abstract

The percolation thresholds of carbon black-polymer composites have been successfully lowered using particulate polymer starting materials (i.e., latex and waterdispersible powder). Composites prepared using carbon black (CB) and commercial poly(vinyl acetate) (PVAc) latex exhibit a percolation threshold near 2.5 vol % CB. This threshold value is significantly lower than that of a comparable reference composite made from poly(N-vinylpyrrolidone) (PNVP) solution and the same CB, which exhibits a sharp rise in electrical conductivity near 15 vol % CB. This dramatic difference in critical CB concentration results from the segregated microstructure induced by the latex during composite film formation. Carbon black particles are forced into conductive pathways at low concentration because of their inability to occupy volume already claimed by the much larger latex particles. There appears to be good qualitative agreement between experimental findings and current models dealing with conductive behavior of composites with segregated microstructures. Lack of quantitative agreement with the models is attributed to the polydispersity of the polymer particles in the latex.

Original languageEnglish (US)
Pages (from-to)692-705
Number of pages14
JournalJournal of Applied Polymer Science
Volume80
Issue number4
DOIs
StatePublished - Apr 25 2001

Keywords

  • Carbon black
  • Electrically conductive
  • Latex
  • Percolation threshold
  • Polymer composite

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