Lithium ion insertion in porous metal oxides

Boone B. Owens; Stefane Passerini; William H. Smyrl

doi:10.1016/S0013-4686(99)00205-4

Lithium ion insertion in porous metal oxides

Boone B. Owens, Stefane Passerini, William H. Smyrl

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

125 Scopus citations

Abstract

Sol-gel processing of transition metal oxide precursors has been used to produce porous materials of high surface area. The technique has permitted the synthesis of solid amorphous vanadium and manganese oxides that are capable of reversibly intercalating large amounts of lithium ions. Therefore, these materials may function as high capacity (500-600 mAh/g), high-energy positive electrodes in lithium batteries. Methods to improve the kinetics and the cycle performance of these positive electrodes are showing promise.

Original language	English (US)
Pages (from-to)	215-224
Number of pages	10
Journal	Electrochimica Acta
Volume	45
Issue number	1
DOIs	https://doi.org/10.1016/S0013-4686(99)00205-4
State	Published - Sep 30 1999

Bibliographical note

Funding Information:
We gratefully acknowledge financial support from the US Army Research Office (DAA-H04-93-R-BAA10, subcontract from Minority Institute Research Hub at IIT) and the Department of Energy (DE-FG02-93ER14384) for the research on high-energy electrode materials.

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abstract = "Sol-gel processing of transition metal oxide precursors has been used to produce porous materials of high surface area. The technique has permitted the synthesis of solid amorphous vanadium and manganese oxides that are capable of reversibly intercalating large amounts of lithium ions. Therefore, these materials may function as high capacity (500-600 mAh/g), high-energy positive electrodes in lithium batteries. Methods to improve the kinetics and the cycle performance of these positive electrodes are showing promise.",

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note = "Funding Information: We gratefully acknowledge financial support from the US Army Research Office (DAA-H04-93-R-BAA10, subcontract from Minority Institute Research Hub at IIT) and the Department of Energy (DE-FG02-93ER14384) for the research on high-energy electrode materials.",

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AU - Passerini, Stefane

AU - Smyrl, William H.

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N2 - Sol-gel processing of transition metal oxide precursors has been used to produce porous materials of high surface area. The technique has permitted the synthesis of solid amorphous vanadium and manganese oxides that are capable of reversibly intercalating large amounts of lithium ions. Therefore, these materials may function as high capacity (500-600 mAh/g), high-energy positive electrodes in lithium batteries. Methods to improve the kinetics and the cycle performance of these positive electrodes are showing promise.

AB - Sol-gel processing of transition metal oxide precursors has been used to produce porous materials of high surface area. The technique has permitted the synthesis of solid amorphous vanadium and manganese oxides that are capable of reversibly intercalating large amounts of lithium ions. Therefore, these materials may function as high capacity (500-600 mAh/g), high-energy positive electrodes in lithium batteries. Methods to improve the kinetics and the cycle performance of these positive electrodes are showing promise.

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Lithium ion insertion in porous metal oxides

Abstract

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