Liquid crystal alignment behaviours on poly(methyl methacrylate) having polyhedral oligomeric silsesquioxane groups

Hyo Kang, Hyunkee Hong, Dong Gyun Kim, Eun Ho Sohn, Jimin Shim, Daeseung Kang, Jong Chan Lee

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

A series of poly(methyl methacrylate) derivatives containing polyhedral oligomeric silsesquioxane (POSS) groups (MCP#) were synthesised via free radical polymerisation (FRP) using methacryl isobutyl POSS (MA-POSS) and methyl methacrylate as monomers to investigate liquid crystal (LC) alignment property of these polymer films. The LC cells made from the films of the polymers having 100 mol% of MA-POSS units (MCP100) showed vertical LC alignment having a pretilt angle of about 90°. The vertical LC alignment behaviour on the MCP100 film was ascribed to the very hydrophobic MCP100 surface having the surface energy value smaller than about 23 mJ/m2 generated by the nonpolar bulky POSS group. Good electro-optical characteristics, such as voltage holding ratio (VHR) and residual DC voltage (R-DC), were observed for the LC cells fabricated using MCP100 as a LC alignment layer.

Original languageEnglish (US)
Pages (from-to)32-40
Number of pages9
JournalLiquid Crystals
Volume42
Issue number1
DOIs
StatePublished - Jan 2 2015

Bibliographical note

Funding Information:
This research was supported by the Technology Innovation Program [grant number 10045221] funded by the Ministry of Trade, Industry and Energy (MOTIE, Korea).

Publisher Copyright:
© 2014 Taylor & Francis.

Copyright:
Copyright 2015 Elsevier B.V., All rights reserved.

Keywords

  • alignment
  • liquid crystal
  • polyhedral oligomeric silsesquioxane
  • vertical

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