Large Spin-state changes in isostructural cyanate-and azide-bridged Mn 3 IIIMn2 II single-molecule magnets

Patrick L. Feng, Casey J. Stephenson, Asma Amjad, Gavin Ogawa, Enrique Del Barco, David N. Hendrickson

Research output: Contribution to journalArticlepeer-review

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Abstract

We prepared three structurally related Mn3 IIIMn 2 II complexes that possess S ≈ 1-11 spin ground states as a result of variations in the geometry and identity of μ 2-η 11 bridging groups. These complexes function as single-molecule magnets yet demonstrate other interesting behavior such as quasi-classical magnetization hysteresis and comparable magnetization reversal barriers (Ueff).

Original languageEnglish (US)
Pages (from-to)1304-1306
Number of pages3
JournalInorganic Chemistry
Volume49
Issue number4
DOIs
StatePublished - Feb 15 2010

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